Manganese-doped carbon quantum dots-based fluorescent probe for selective and sensitive sensing of 2,4,6-trinitrophenol via an inner filtering effect

In the present work, a selective and sensitive method for detecting TNP using manganese doped carbon quantum dots (Mn-CDs) was developed. The Mn-CDs were prepared via a simple hydrothermal method using 1-(2-pyridinylazo)-2-naohthalenol naohthalenol (PAN) and MnCl2 as precursors. The as-prepared Mn-CDs have UV emission with high quantum yield (83.2%). Because of the strong characteristic absorption of TNP at 356 nm, which has good spectral overlap with the emission peak of Mn-CDs, the fluorescence intensity of Mn-CDs at 360 nm is linearly quenched in the presence of TNP in the concentration range of 0.1-200 mu M. The developing assay based on an inner filter effect (IFE) mechanism for detecting TNP is selective, convenient, and shows that the as-prepared Mn-CDs have application prospects for simple and specific analytical chemistry. (C) 2018 Elsevier B.V. All rights reserved.