Addition reactions of E-E and E-H bonds to triple bond of alkynes catalyzed by Pd, Pt, and Ni complexes (E=S, Se)

被引：69

作者：

Beletskaya, Irina P. ^{[1
]}

Ananikov, Valentine P.

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[2] Russian Acad Sci, Zelinsky Inst Organ Chem, Moscow 119991, Russia

来源：

PURE AND APPLIED CHEMISTRY | 2007年 / 79卷 / 06期

关键词：

addition reactions; green chemistry; transition-metal catalysis; sulfur species; selenium species;

D O I：

10.1351/pac200779061041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthetic application and mechanistic aspects of transition-metal (Ni, Pd, Pt) catalyzed addition of E-E and E-H (E=S, Se) bonds to alkynes were investigated in detail. This study revealed major factors controlling the selectivity of such addition reactions. A new Ni-based catalytic system with a self-organized nanostructured catalyst has been designed to perform chemical transformation in high yield, under mild conditions.

引用

页码：1041 / 1056

页数：16

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