Study of (2,0) band of A2Πu-X2Σg+ system of N2+ by optical heterodyne detected velocity modulation spectroscopy

被引：12

作者：

Wu, Yan-dan

Ben, Jin-wen

Li, Ling

Zhen, Li-juan

Chen, Yang-qin

Yang, Xiao-hua ^{[1
]}

机构：

[1] E China Normal Univ, Key Lab Opt & Magnet Resonance Spect, Minist Educ, Shanghai 200062, Peoples R China

[2] E China Normal Univ, Dept Phys, Shanghai 200062, Peoples R China

[3] Hanshan Normal Univ, Dept Phys & Elect Engn, Chaozhou 521041, Peoples R China

来源：

CHINESE JOURNAL OF CHEMICAL PHYSICS | 2007年 / 20卷 / 03期

关键词：

N-2+ molecular ion; spectrum; molecular constant;

D O I：

10.1088/1674-0068/20/03/285-290

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The (2, 0) band of the A(2)Pi(u)-X-2 Sigma(+)(g) system of N-2(+) was rotationally studied via optical heterodyne detected velocity modulation spectroscopy. Owing to the high sensitivity of the spectroscopy employed, the frequencies of 310 lines of this band were accurately determined. Moreover, those overlapped lines were also well determined via deconvolution method. A nonlinear least-squares fitting procedure using a standard Hamiltonian was applied to analyze this band. Therefore, the most accurate molecular constants were obtained.

引用

收藏

页码：285 / 290

页数：6

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