A rare diarboxylate and N-oxide/H2O bridged metal-organic framework with nickel(II)-oxide octahedral chains: synthesis, crystal structure, and magnetic properties with theoretical investigations on the exchange mechanism

被引：4
作者：
An, Bing [1 ]
Bai, Yan [1 ,2 ]
Wang, Jun-Li [1 ]
Dang, Dong-Bin [1 ]
机构：
[1] Henan Univ, Inst Mol & Crystal Engn, Sch Chem & Chem Engn, Henan Key Lab Polyoxometalate Chem, Kaifeng 475004, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
MATERIALS LETTERS | 2015年 / 141卷
基金：
中国国家自然科学基金;
关键词：
Nickel(II); Metal chain; Co-ligands; Crystal structure; Magnetic properties; COORDINATION POLYMERS; N; N'-DIOXIDE; ACID;
D O I：
10.1016/j.matlet.2014.11.127
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
One 3D metal-organic framework {[Ni-2(1,4-NDC)(2)(4,4'-dpdo)(H2O)]center dot 3 H2O}(n) 1 (1,4-H2NDC=1,4-naphthalenedicarboxylate acid and 4,4'-dpdo=4,4'-Dipyridyl-N,N'-dioxide) has been hydrothermally synthesized and well-characterized. Polymer 1 arranges in the (IO1)-O-1 fashion. The hexacoordinated Ni(II) centers are triply bridged by two 1,4-NDC2- carboxylate group plus mu-4,4-dpdo or mu-H2O to form an alternating chain. Each metal chain is cross-connected to four other chains to shape a 3D network. Magnetic studies show that 1 exhibits dominant ferromagnetic interactions with intrachain alternating antiferromagnetic/ferromagnetic interactions. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：280 / 283
页数：4
相关论文
共 16 条
[1]   Cation-size-controlled assembly of the Ni(Ac)2-1,4-H2NDC system: geminal dicationic ionothermal syntheses, crystal structures and magnetic properties [J].
An, Bing ;
Bai, Yan ;
Wang, Jun-Li ;
Dang, Dong-Bin .
DALTON TRANSACTIONS, 2014, 43 (34) :12828-12831
[2]   Structural versatility and luminescent properties in d10 metal ion polymers with 1,4-naphthalenedicarboxylate acid and 4,4′-dipyridyl N,N′-dioxide [J].
An, Bing ;
Zhou, Ruimin ;
Dang, Dongbin ;
Wang, Junli ;
Pan, Hui ;
Bai, Yan .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2014, 122 :392-399
[3]   Effects of halogen bonding in ferromagnetic chains based on Co(II) coordination polymers [J].
Clemente-Juan, Juan M. ;
Coronado, Eugenio ;
Minguez Espallargas, Guillermo ;
Adams, Harry ;
Brammer, Lee .
CRYSTENGCOMM, 2010, 12 (08) :2339-2342
[4]   One-pot solvothermal synthesized enhanced magnetic zinc ferrite-reduced graphene oxide composite material as adsor bent for methylene blue removal [J].
Fei, Peng ;
Zhong, Ming ;
Lei, Ziqiang ;
Su, Bitao .
MATERIALS LETTERS, 2013, 108 :72-74
[5]  
Gu Z-G, 2008, DALTON T, V5, P593
[6]   One novel three-dimensional framework constructed from infrequent μ-O metal chains with alternating antiferromagnetic/ferromagnetic interactions [J].
Li, Haiyan ;
An, Bing ;
Bai, Yan ;
Wang, Junli ;
Pan, Hui ;
Dang, Dongbin .
SYNTHETIC METALS, 2014, 194 :126-131
[7]   Cobalt(ii)-(dpyo)-dicarboxylate networks: Unique H-bonded assembly and rare bridging mode of dpyo in one of them [dpyo = 4,4′-dipyridyl N,N′-dioxide] [J].
Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata 7000 32, India ;
不详 ;
不详 .
Dalton Trans., 2007, 14 (1383-1391) :1383-1391
[8]   High freezing temperature in SnO2 based diluted magnetic semiconductor [J].
Mounkachi, O. ;
El Moussaoui, H. ;
Masrour, R. ;
Ilali, J. ;
EL Mediouri, K. ;
Hamedoun, M. ;
Hlil, E. K. ;
El Kenz, A. ;
Benyoussef, A. .
MATERIALS LETTERS, 2014, 126 :193-196
[9]   Characterization of hybrid molecular material prepared by 1-butyl 3-methyl imidazolium bromide and phosphotungstic acid [J].
Rajkumar, T. ;
Rao, G. Ranga .
MATERIALS LETTERS, 2008, 62 (25) :4134-4136
[10]   Solvent-modulated slow magnetic relaxation in a two-dimensional compound composed of cobalt(II) single-chain magnets [J].
Wang, Yan-Qin ;
Sun, Wei-Wei ;
Wang, Zhen-Dong ;
Jia, Qin-Xiang ;
Gao, En-Qing ;
Song, You .
CHEMICAL COMMUNICATIONS, 2011, 47 (22) :6386-6388
12