Synthesis and magnetic properties of Co1-xZnxFe2O4+γ nanoparticles as materials for magnetic fluid hyperthermia

被引:45
作者
Veverka, M. [1 ]
Veverka, P. [1 ]
Jirak, Z. [1 ]
Kaman, O. [1 ,2 ]
Knizek, K. [1 ]
Marysko, M. [1 ]
Pollert, E. [1 ]
Zaveta, K. [1 ]
机构
[1] AS CR, Inst Phys, VVI, Prague 16253 6, Czech Republic
[2] Charles Univ Prague, Fac Sci, Dept Inorgan Chem, Prague 12840 2, Czech Republic
关键词
Magnetic nanoparticle; Cobalt zinc ferrite; Precipitation; Magnetic behavior; Magnetic fluid hyperthermia; COBALT FERRITE NANOPARTICLES; COPRECIPITATION METHOD; COFE2O4; NANOPARTICLES; SUPERPARAMAGNETISM; PARTICLES; ROUTE;
D O I
10.1016/j.jmmm.2010.02.042
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanoparticles of the single spinel phase Co1-xZnxFe2O4+gamma of mean size 3-23 nm, as determined by X-ray diffraction analysis, were synthesized by the co-precipitation method followed by a temperature treatment. Magnetic studies carried out in the range of 4.5-550 K revealed gradual transition from ferrimagnetic to superparamagnetic to paramagnetic behaviour depending on the composition and particle size. The observed behaviour indicates a broad distribution of volume sizes of the nanoparticles. Particular importance can be ascribed to the composition of x = 0.6 where the observed transition temperature to the paramagnetic state at 310-334 K suggests applicability of this material for magnetic fluid hyperthermia in a self-controlled regime. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:2386 / 2389
页数:4
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