Covalent Organic Frameworks: A Molecular Platform for Designer Polymeric Architectures and Functional Materials

被引：40

作者：

Jiang, Donglin ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, 3 Sci Dr 3, Singapore 117543, Singapore

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2021年 / 94卷 / 04期

关键词：

Covalent organic frameworks; Two-dimensional polymers; Design and synthesis; CRYSTALLINE; LUMINESCENT; NANOTUBES; ELECTRON; DYNAMICS;

D O I：

10.1246/bcsj.20200389

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Covalent organic frameworks comprise a class of polymer which covalently links organic units into well-defined architectures to create ordered structures and offers an irreplaceable platform for designing organic/polymeric materials. In this award account, we trace our paths and show our initiatives to explore this class of molecular frameworks, by establishing design principle and synthetic strategies and developing functions and properties. By elucidating interplays of ordered structures with photons, excitons, electrons, holes, ions and molecules, we scrutinize unique structural features and functions which are specific to the ordered structures. We predict the key fundamental issues to be addressed in future and show the directions from perspectives of chemistry, physics, and materials science.

引用

页码：1215 / 1231

页数：17

共 86 条

[1] Vinylene-Linked Covalent Organic Frameworks by Base-Catalyzed Aldol Condensation [J].

Acharjya, Amitava ;

Pachfule, Pradip ;

Roeser, Jerome ;

Schmitt, Franz-Josef ;

Thomas, Arne .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (42) :14865-14870

[2] An azine-linked hexaphenylbenzene based covalent organic framework [J].

Alahakoon, Sampath B. ;

Thompson, Christina M. ;

Nguyen, Amy X. ;

Occhialini, Gino ;

McCandless, Gregory T. ;

Smaldone, Ronald A. .

CHEMICAL COMMUNICATIONS, 2016, 52 (13) :2843-2845

[3] Two-dimensional semiconducting covalent organic frameworks via condensation at arylmethyl carbon atoms [J].

Bi, Shuai ;

Yang, Can ;

Zhang, Wenbei ;

Xu, Junsong ;

Liu, Lingmei ;

Wu, Dongqing ;

Wang, Xinchen ;

Han, Yu ;

Liang, Qifeng ;

Zhang, Fan .

NATURE COMMUNICATIONS, 2019, 10 (1)

[4]

Bursten B.E., 1999, CHEM CENTRAL SCI

[5] Photoelectric Covalent Organic Frameworks: Converting Open Lattices into Ordered Donor-Acceptor Heterojunctions [J].

Chen, Long ;

Furukawa, Ko ;

Gao, Jia ;

Nagai, Atsushi ;

Nakamura, Toshikazu ;

Dong, Yuping ;

Jiang, Donglin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (28) :9806-9809

[6] Designed synthesis of double-stage two-dimensional covalent organic frameworks [J].

Chen, Xiong ;

Addicoat, Matthew ;

Jin, Enquan ;

Xu, Hong ;

Hayashi, Taku ;

Xu, Fei ;

Huang, Ning ;

Irle, Stephan ;

Jiang, Donglin .

SCIENTIFIC REPORTS, 2015, 5

[7] Locking Covalent Organic Frameworks with Hydrogen Bonds: General and Remarkable Effects on Crystalline Structure, Physical Properties, and Photochemical Activity [J].

Chen, Xiong ;

Addicoat, Matthew ;

Jin, Enquan ;

Zhai, Lipeng ;

Xu, Hong ;

Huang, Ning ;

Guo, Zhaoqi ;

Liu, Lili ;

Irle, Stephan ;

Jiang, Donglin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (09) :3241-3247

[8] Control of Crystallinity and Porosity of Covalent Organic Frameworks by Managing Interlayer Interactions Based on Self-Complementary π-Electronic Force [J].

Chen, Xiong ;

Addicoat, Matthew ;

Irle, Stephan ;

Nagai, Atsushi ;

Jiang, Donglin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (02) :546-549

[9] Highly Emissive Covalent Organic Frameworks [J].

Dalapati, Sasanka ;

Jin, Enquan ;

Addicoat, Matthew ;

Heine, Thomas ;

Jiang, Donglin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (18) :5797-5800

[10] Rational design of crystalline supermicroporous covalent organic frameworks with triangular topologies [J].

Dalapati, Sasanka ;

Addicoat, Matthew ;

Jin, Shangbin ;

Sakurai, Tsuneaki ;

Gao, Jia ;

Xu, Hong ;

Irle, Stephan ;

Seki, Shu ;

Jiang, Donglin .

NATURE COMMUNICATIONS, 2015, 6

← 1 2 3 4 5 6 7 8 9 →