A very simple and highly efficient procedure for N-formylation of primary and secondary amines at room temperature under solvent-free conditions

被引：121
|
作者：
Brahmachari, Goutam [1 ]
Laskar, Sujay [1 ]
机构：
[1] Visva Bharati Univ, Dept Chem, Santini Ketan 731235, W Bengal, India
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 17期
关键词：
N-Formylation; Amines; Sodium formate; Formic acid; Room temperature; Solvent-free; STEREOSELECTIVE SYNTHESIS; DERIVATIVES; ESTERS; ACID; DIMETHYLFORMAMIDE; ISOCYANIDES; REAGENTS; FORMATE; FACILE; AGENT;
D O I：
10.1016/j.tetlet.2010.02.119
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
N-Formylation of primary and secondary amines has efficiently been carried out at room temperature in excellent yields by using catalytic amount of sodium formate in formic acid under solvent-free conditions. The process is remarkably simple and environmentally benign. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2319 / 2322
页数：4
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