Surface grafting of octylamine onto poly(ethylene-alt-maleic anhydride) gate insulators for low-voltage DNTT thin-film transistors

被引:9
作者
Choe, Yun-Seo [1 ,2 ]
Yi, Mi Hye [1 ]
Kim, Ji-Heung [2 ]
Kim, Yun Ho [1 ]
Jang, Kwang-Suk [3 ]
机构
[1] Korea Res Inst Chem Technol, Div Adv Mat, Daejeon 34114, South Korea
[2] Sungkyunkwan Univ, Sch Chem Engn, Suwon 16419, South Korea
[3] Hankyong Natl Univ, Dept Chem Engn, Anseong 17579, South Korea
关键词
FIELD-EFFECT TRANSISTORS; ORGANIC-TRANSISTOR; HIGH-MOBILITY; STRUCTURAL ORDER; PERFORMANCE; STABILITY; COPOLYMER; PRESSURE; SENSORS;
D O I
10.1039/c5cp06320e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study investigates a spin-coating method for modifying the surface properties of a poly(ethylene-alt-maleic anhydride) (PEMA) gate insulator. The 60 nm-thick PEMA thin film exhibits excellent electrical insulating properties, and its surface properties could be easily modified by surface grafting of octylamine. Due to surface treatment via spin-coating, the surface energy of the PEMA gate insulator decreased, the crystal quality of the organic semiconductor improved, and consequently the performance of low-voltage organic thin-film transistors (TFTs) was enhanced. Our results suggest that the surface treatment of the PEMA gate insulator could be a simple and effective method for enhancing the performance of organic TFTs.
引用
收藏
页码:8522 / 8528
页数:7
相关论文
共 39 条
  • [1] Materials requirements and fabrication of active matrix arrays of organic thin-film transistors for displays
    Chabinyc, ML
    Salleo, A
    [J]. CHEMISTRY OF MATERIALS, 2004, 16 (23) : 4509 - 4521
  • [2] A Pseudo-Regular Alternating Conjugated Copolymer Using an Asymmetric Monomer: A High-Mobility Organic Transistor in Nonchlorinated Solvents
    Choi, Hyun Ho
    Baek, Jang Yeol
    Song, Eunjoo
    Kang, Boseok
    Cho, Kilwon
    Kwon, Soon-Ki
    Kim, Yun-Hi
    [J]. ADVANCED MATERIALS, 2015, 27 (24) : 3626 - 3631
  • [3] Spatially correlated charge transport in organic thin film transistors
    Dinelli, F
    Murgia, M
    Levy, P
    Cavallini, M
    Biscarini, F
    de Leeuw, DM
    [J]. PHYSICAL REVIEW LETTERS, 2004, 92 (11) : 116802 - 1
  • [4] Design of Novel Dielectric Surface Modifications for Perylene Thin-Film Transistors
    Effertz, Christian
    Lahme, Stefan
    Schulz, Philip
    Segger, Ingolf
    Wuttig, Matthias
    Classen, Arno
    Bolm, Carsten
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (02) : 415 - 420
  • [5] Tuning charge transport in solution-sheared organic semiconductors using lattice strain
    Giri, Gaurav
    Verploegen, Eric
    Mannsfeld, Stefan C. B.
    Atahan-Evrenk, Sule
    Kim, Do Hwan
    Lee, Sang Yoon
    Becerril, Hector A.
    Aspuru-Guzik, Alan
    Toney, Michael F.
    Bao, Zhenan
    [J]. NATURE, 2011, 480 (7378) : 504 - U124
  • [6] High-performance dinaphtho-thieno-thiophene single crystal field-effect transistors
    Haas, Simon
    Takahashi, Yukihiro
    Takimiya, Kazuo
    Hasegawa, Tatsuo
    [J]. APPLIED PHYSICS LETTERS, 2009, 95 (02)
  • [7] Strain-effect for controlled growth mode and well-ordered structure of quaterrylene thin films
    Hayakawa, Ryoma
    Turak, Ayse
    Zhang, XueNa
    Hiroshiba, Nobuya
    Dosch, Helmut
    Chikyow, Toyohiro
    Wakayama, Yutaka
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2010, 133 (03)
  • [8] X-RAY MEASUREMENTS OF DISLOCATION DENSITY IN DEFORMED COPPER AND ALUMINUM SINGLE CRYSTALS
    HORDON, MJ
    AVERBACH, BL
    [J]. ACTA METALLURGICA, 1961, 9 (03): : 237 - 246
  • [9] Liquid crystals for organic thin-film transistors
    Iino, Hiroaki
    Usui, Takayuki
    Hanna, Jun-ichi
    [J]. NATURE COMMUNICATIONS, 2015, 6
  • [10] Surface modification of polyimide gate insulators for solution-processed 2,7-didecyl[1]benzothieno[3,2-b][1]benzothiophene (C10-BTBT) thin-film transistors
    Jang, Kwang-Suk
    Kim, Won Soo
    Won, Jong-Myung
    Kim, Yun-Ho
    Myung, Sung
    Ka, Jae-Won
    Kim, Jinsoo
    Ahn, Taek
    Yi, Mi Hye
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (03) : 950 - 956