Membrane manufacturing via simultaneous electrospinning of PAN and PSU solutions

被引:9
作者
Guclu, Serkan [1 ,2 ]
Pasaoglu, Mehmet Emin [1 ,2 ]
Koyuncu, Ismail [1 ,2 ]
机构
[1] Istanbul Tech Univ, Turkish Natl Res Ctr Membrane Technol MEM TEK, TR-80626 Istanbul, Turkey
[2] Istanbul Tech Univ, Dept Environm Engn, TR-80626 Istanbul, Turkey
关键词
Nanofiber; Polyacrylonitrile; Heat treatment; Polysulfone; Simultaneous electrospinning; WATER; COMPOSITE; MATS; NANO;
D O I
10.1080/19443994.2015.1024747
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Even though nanofiber membranes have wide unique characteristics, such as high surface porosity, high flux ratios, and lower production costs, they still show some shortcomings in terms of irreversible clogging, large pore sizes, and nanofiber rupture during filtration. This paper addresses a study to overcome such limitations with simultaneous electrospinning technique. Two different types of nanofibers were collected on the same layer. Polyacrylonitrile (PAN) nanofiber membranes have lower pore size than polysulfone (PSU) nanofiber membranes, while PSU component allowed easier toughening since it requires lower temperature for mechanical improvement against fiber rupture. As a result, pore size of simultaneous nanofiber membranes was provided by PAN (around 0.8 mu m), whereas heat treatment at 185 degrees C improved the strength of nanofiber membranes against rupture during filtration. Wastewater and surface water were filtered for filtration characterization. For both, removal rates were great. Thermal treatment improved membranes against fiber rupture. While fibers of heat-treated membrane were not broken, non-heat-treated membranes' fibers were broken and membrane disintegrated. But significant irreversible fouling was observed in wastewater filtration.
引用
收藏
页码:8152 / 8160
页数:9
相关论文
共 18 条
[1]   Assessment and optimization of electrospun nanofiber-membranes in a membrane bioreactor (MBR) [J].
Bilad, M. R. ;
Westbroek, P. ;
Vankelecom, Ivo F. J. .
JOURNAL OF MEMBRANE SCIENCE, 2011, 380 (1-2) :181-191
[2]   Performance assessment of electrospun nanofibers for filter applications [J].
Bjorge, Decostere ;
Daels, Nele ;
De Vrieze, Sander ;
Dejans, Pascal ;
Van Camp, Tamara ;
Audenaert, Wim ;
Hogie, Joel ;
Westbroek, Philippe ;
De Clerck, Karen ;
Van Hulle, Stijn W. H. .
DESALINATION, 2009, 249 (03) :942-948
[3]   Potential of a functionalised nanofibre microfiltration membrane as an antibacterial water filter [J].
Daels, N. ;
De Vrieze, S. ;
Sampers, I. ;
Decostere, B. ;
Westbroek, P. ;
Dumoulin, A. ;
Dejans, P. ;
De Clerck, K. ;
Van Hulle, S. W. H. .
DESALINATION, 2011, 275 (1-3) :285-290
[4]   Fabrication of blend biodegradable nanofibrous nonwoven mats via multi-jet electrospinning [J].
Ding, B ;
Kimura, E ;
Sato, T ;
Fujita, S ;
Shiratori, S .
POLYMER, 2004, 45 (06) :1895-1902
[5]   Production of drinking water from saline water by air-gap membrane distillation using polyvinylidene fluoride nanofiber membrane [J].
Feng, C. ;
Khulbe, K. C. ;
Matsuura, I. ;
Gopal, R. ;
Kaur, S. ;
Rarnakrishna, S. ;
Khayet, M. .
JOURNAL OF MEMBRANE SCIENCE, 2008, 311 (1-2) :1-6
[6]   Electrospun nanofibrous polysulfone membranes as pre-filters: Particulate removal [J].
Gopal, Renuga ;
Kaur, Satinderpal ;
Feng, Chao Yang ;
Chan, Casey ;
Ramakrishna, Seeram ;
Tabe, Shahram ;
Matsuura, Takeshi .
JOURNAL OF MEMBRANE SCIENCE, 2007, 289 (1-2) :210-219
[7]   Electrospun nanofibrous filtration membrane [J].
Gopal, Renuga ;
Kaur, Satinderpal ;
Ma, Zuwei ;
Chan, Casey ;
Ramakrishna, Seeram ;
Matsuura, Takeshi .
JOURNAL OF MEMBRANE SCIENCE, 2006, 281 (1-2) :581-586
[8]   Preparation and structures of electrospun PAN nanofibers as a precursor of carbon nanofibers [J].
Gu, SY ;
Ren, J ;
Wu, QL .
SYNTHETIC METALS, 2005, 155 (01) :157-161
[9]   Preparation of polyurethane cationomer nanofiber mats for use in antimicrobial nanofilter applications [J].
Jeong, Eun Hwan ;
Yang, He ;
Youk, Ji Ho .
MATERIALS LETTERS, 2007, 61 (18) :3991-3994
[10]   Influence of electrospun fiber size on the separation efficiency of thin film nanofiltration composite membrane [J].
Kaur, Satinderpal ;
Sundarrajan, Subramanian ;
Rana, Dipak ;
Matsuura, Takeshi ;
Ramakrishna, Seeram .
JOURNAL OF MEMBRANE SCIENCE, 2012, 392 :101-111