Highly functionalized tetrathiafulvalenes:: Riding along the synthetic trail from electrophilic alkynes

被引：161

作者：

Gorgues, A ^{[1
]}

Hudhomme, P ^{[1
]}

Sallé, M ^{[1
]}

机构：

[1] Univ Angers, CNRS, UMR 6200, Lab Chim Ingn Mol & Mat Angers, F-49045 Angers, France

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 11期

关键词：

D O I：

10.1021/cr0306485

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

To date, interest on tetrathiafulvalene (TTF) has greatly increased. This review gives an updated vision of synthetic aspects in the field of the TTF chemistry. As a guideline, the central role of electrophilic alkynes in the synthesis of 1,3-dithiole and TTF systems is considered. Focus is on dimethyl acetylenedicarboxylate (DMAD) and acetylenedicarbaldehyde (ADCA) or its monodiethylacetal (ADCA-MA). The general reactivity of electrophilic alkynes leading to 1,3-dithiole or TTF derivatives is discussed, followed by the discovery of ADCA and its synthetic applications in this field.

引用

页码：5151 / 5184

页数：34

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