The factors affecting the performance of activated carbon prepared from oil palm empty fruit bunches for adsorption of phenol

被引:88
作者
Alam, Md Zahangir [1 ]
Ameem, Emad S. [1 ]
Muyibi, Suleyman A. [1 ]
Kabbashi, Nassereldeen A. [1 ]
机构
[1] Int Islamic Univ Malaysia, Fac Engn, BERU, Dept Biotechnol Engn, Kuala Lumpur 50728, Malaysia
关键词
Oil palm empty fruit bunches; Activated carbon; Adsorption; Phenol; Statistical optimization; Thermal activation; COCONUT HUSK; RICE-HUSK; REMOVAL; OPTIMIZATION;
D O I
10.1016/j.cej.2009.07.033
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Powdered activated carbons (PACs) were produced from oil palm empty fruit bunches (EFB) by varying the operating parameters of temperatures, CO2 gas flow rates and activation times using 2-level full factorial experimental design. The EFB samples were first carbonized for 30 min using nitrogen gas followed by physical activation using CO2 to optimize best production conditions. The optimum conditions for PACs produced were investigated through adsorption tests on aqueous solution of phenol. The results of this study demonstrated that the activation temperature with the range of 800-900 degrees C had the most significant effect on the adsorption characteristics as well as the yield of the activated carbon produced. Based on the analysis of variance (ANOVA) and model equation developed, the optimum production conditions for the EFB PAC were found to be at the activation temperature of 900 degrees C with CO2 gas flow rate of 0.1 L/min and activation time of 15 min. Characterization of PAC produced showed that the activation conditions would find good-quality adsorbent with the BTE surface area of 345.1 m(2)/g and well forming pores distribution. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:191 / 198
页数:8
相关论文
共 29 条
[1]   Treatability of s-triazine herbicide metabolites using powdered activated carbon [J].
Adams, CD ;
Watson, TL .
JOURNAL OF ENVIRONMENTAL ENGINEERING-ASCE, 1996, 122 (04) :327-330
[2]   Activated carbons derived from oil palm empty-fruit bunches: Application to environmental problems [J].
Alam, Md Zahangir ;
Muyibi, Suleyman A. ;
Mansor, Mariatul F. ;
Wahid, Radziah .
JOURNAL OF ENVIRONMENTAL SCIENCES, 2007, 19 (01) :103-108
[3]  
Alam MZ, 2006, J ENVIRON SCI, V18, P446
[4]   Production of activated carbon from Luscar char: Experimental and modeling studies [J].
Azargohar, R ;
Dalai, AK .
MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 85 (03) :219-225
[5]  
AZEVEDO DCS, CAVALCANTE MICROPORO
[6]   Utilization of raw and activated date pits for the removal of phenol from aqueous solutions [J].
Banat, F ;
Al-Asheh, S ;
Al-Makhadmeh, L .
CHEMICAL ENGINEERING & TECHNOLOGY, 2004, 27 (01) :80-86
[7]  
Bansal R.C., 1988, ACTIVE CARBON, P1
[8]   Surface functionality and porosity of activated carbons obtained from chemical activation of wood [J].
Benaddi, H ;
Bandosz, TJ ;
Jagiello, J ;
Schwarz, JA ;
Rouzaud, JN ;
Legras, D ;
Béguin, F .
CARBON, 2000, 38 (05) :669-674
[10]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319