Synthesis and characterizations of tin(IV)trithiophosphates and their adducts with nitrogen donor bases

被引：1
|
作者：
Tripathi, U. N. [1 ]
Sharma, D. K.
Jain, Nisha
Soni, M.
机构：
[1] DDU Univ, Dept Chem, Gorakhpur, Uttar Pradesh, India
[2] Govt Arts & Sci Coll, Dept Chem, Ratlam, MP, India
[3] Mandsaur Inst Pharm, Mandsaur, MP, India
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2007年 / 182卷 / 05期
关键词：
1,10-phenanthroline; 2,2-bipyridyl; phosphorotrithioate; tin(IV);
D O I：
10.1080/10426500601091063
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Bis-(trithiophosphato)tin(IV) [(RO)P(S)S-2](2)Sn (where R = n-C3H7,i-C3H7,i-C3H7, i-C5H11,-C6H5) were prepared by a reaction of methanolic solution of SnCl4 and dipotassium salt of trithiophosphates in a 1:2 molar ratio, and their adducts [(RO)P(S)S-2](2)Sn. N2C12H8 and [(RO)P(S)S-2](2)Sn. N2C10H8 were prepared by a reaction of methanolic solution of [(RO)P(S)S-2](2)Sn and N-donor bases in a 1:1 molar ratio. These newly synthesized derivatives have been characterized by elemental analysis; molecular weight measurement; and IR, C-13, P-31, and Sn-119 NMR spectral studies. A coordination number of four and six is suggested for trithiophosphates of tin(IV) and their adducts with N-donor bases, respectively.
引用
收藏
页码：1033 / 1044
页数：12
相关论文
共 50 条
  • [41] ADDUCTS OF SOME NITROGEN BASES WITH NICKEL(II) PICROLONATES
    LORENZOTTI, A
    CINGOLANI, A
    LEONESI, D
    BONATI, F
    GAZZETTA CHIMICA ITALIANA, 1984, 114 (1-2): : 31 - 33
  • [42] TIN(IV) AND ORGANOTIN(IV) ADDUCTS OF BIS(1-PYRAZOLYL)METHANE
    LOBBIA, GG
    CINGOLANI, A
    LEONESI, D
    LORENZOTTI, A
    BONATI, F
    INORGANICA CHIMICA ACTA, 1987, 130 (02) : 203 - 207
  • [43] ADDUCTS OF BIS(ACETYLACETONATO) AND BIS(TRIFLUOROACETYLACETONATO) OXOVANADIUM(IV) WITH 1,10-PHENANTHROLINE AND RELATED NITROGEN BASES
    ISOBE, K
    NAKAMURA, Y
    KAWAGUCHI, S
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1978, 40 (04): : 607 - 611
  • [44] BIS(XYLENEDITHIOCARBOXYLATE)OXOVANADIUM(IV) AND ADDUCTS WITH ORGANIC-BASES
    VILLAREJO, ALD
    RAGEL, CV
    CUEVAS, GP
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1992, 22 (05): : 599 - 614
  • [45] SYNTHESIS AND THERMAL-PROPERTIES OF ADDUCTS OF TRIMETHYLINDIUM WITH NITROGEN-CONTAINING LEWIS-BASES
    FOSTER, DF
    RUSHWORTH, SA
    COLEHAMILTON, DJ
    CAFFERTY, R
    HARRISON, J
    PARKES, P
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (01): : 7 - 11
  • [46] SYNTHESIS AND STRUCTURAL STUDIES OF TIN(II) AND TIN(IV) COMPLEXES OF SCHIFF-BASES DERIVED FROM SULFA DRUGS
    VARSHNEY, A
    TANDON, JP
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1986, 16 (10): : 1371 - 1382
  • [47] Thermochemistry of adducts of tin(IV) bromide with amide and thioamide ligands
    Dunstan, PO
    THERMOCHIMICA ACTA, 2001, 369 (1-2) : 9 - 16
  • [48] TIN(IV) TETRAHALIDE ADDUCTS WITH 4-AMINO-BENZOPHENONE
    VEZZOSI, IM
    ZANOLI, AF
    PEYRONEL, G
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1980, 36 (02) : 219 - 222
  • [49] INFRARED STUDY OF SOME SELENATO DERIVATIVES AND ADDUCTS OF TIN(IV)
    SARR, O
    DIOP, L
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1990, 46 (08): : 1239 - 1244
  • [50] SYNTHESIS AND CHARACTERIZATION OF TITANIUM(IV), TIN(IV) AND LEAD(IV) COMPLEXES OF SCHIFF-BASES DERIVED FROM S-BENZYLDITHIOCARBAZATE
    DEGAONKAR, MP
    GOPINATHAN, S
    GOPINATHAN, C
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1989, 19 (06): : 613 - 625
12345