Hemibuckminsterfullerene C30H12:: X-ray crystal structures of the parent hydrocarbon and of the two-dimensional organometallic network {[Rh2(O2CCF3)4]3•(C30H12)}

被引：98

作者：

Petrukhina, MA ^{[1
]}

Andreini, KW

Peng, LQ

Scott, LT

机构：

[1] SUNY Albany, Dept Chem, Albany, NY 12222 USA

[2] Boston Coll, Merkert Chem Ctr, Dept Chem, Chestnut Hill, MA 02467 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 41期

关键词：

arene ligands; carboxylate ligands; geodesic polyarenes; pi interactions; rhodium;

D O I：

10.1002/anie.200460855

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bringing together two C30 hemispheres by coordinating their concave faces to a monometal template or metal cluster represents the first step in an appealing strategy for the controlled synthesis of endohedral fullerene complexes by laboratory methods. A crystalline transition metal complex of this structural type (see picture; Rh blue, O red, C gray; H, F omitted) has now been prepared from hemibuckminsterfullerene C30H12 and [Rh2(O2CCF3)4].

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页码：5477 / 5481

页数：5

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