High-resolution infrared study of the ν11 band of allene

被引:9
作者
Nissen, S [1 ]
Hegelund, F
Johnson, MS
Nelander, B
机构
[1] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark
[2] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark
[3] Lund Univ, Ctr Chem, Dept Phys Chem, S-22100 Lund, Sweden
关键词
allene; high-resolution infrared spectroscopy; molecular constants;
D O I
10.1006/jmsp.2002.8596
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The high-resolution infrared spectrum of allene has been observed in the 280-380 cm(-1) region at a nominal resolution of 0.00125 cm(-1) using the IR beamline at the MAX-1 electron storage ring in Lund. The spectrum shows the bending fundamental of the nu(11) band from which spectroscopic constants for the nu(11) level have been obtained. The accompanying hot band component 2nu(11)(2)-nu(11)(1) has also been assigned and analyzed. (C) 2002 Elsevier Science (USA).
引用
收藏
页码:197 / 202
页数:6
相关论文
共 10 条
[1]  
GUELACHVILI G, 1986, HDB INFRARED STANDAR
[2]   REANALYSIS OF THE NU(9), NU(10) BAND SYSTEM IN ALLENE [J].
HEGELUND, F .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1994, 165 (02) :586-587
[3]   HIGH-RESOLUTION INFRARED STUDY OF THE NU(11) LEVEL IN H2C=C-13=CH2 [J].
HEGELUND, F ;
BURGER, H ;
POLANZ, O .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1995, 169 (01) :154-165
[4]   650-1050 CM-1 REGION OF RAMAN-SPECTRUM OF GASEOUS ALLENE [J].
HEGELUND, F ;
ANDERSEN, HB .
JOURNAL OF RAMAN SPECTROSCOPY, 1975, 3 (01) :73-90
[5]  
Hegelund F., 1974, Journal of Raman Spectroscopy, V2, P31, DOI 10.1002/jrs.1250020104
[6]   A HIGH-RESOLUTION INFRARED STUDY OF THE NU(9)+NU(11)-NU(11), NU(10)+NU(11)-NU(11) HOT BAND SYSTEM IN ALLENE [J].
HEGELUND, F ;
ANDRESEN, N ;
KOIVUSAARI, M .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1993, 159 (01) :230-248
[7]   GROUND-STATE CONSTANTS AND K-TYPE DOUBLING FOR ALLENE [J].
HEGELUND, F ;
ANDRESEN, N ;
KOIVUSAARI, M .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1991, 149 (01) :305-313
[8]   High-resolution gas phase spectroscopy with a synchrotron radiation source [J].
Johnson, MS ;
Nelander, B .
NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA D-CONDENSED MATTER ATOMIC MOLECULAR AND CHEMICAL PHYSICS FLUIDS PLASMAS BIOPHYSICS, 1998, 20 (04) :449-462
[9]   HIGH-RESOLUTION FOURIER-TRANSFORM STUDY OF THE PERPENDICULAR BAND-NU-11 OF ALLENE AT 353 CM-1 [J].
PLIVA, J ;
KAUPPINEN, J .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1985, 111 (01) :93-101
[10]  
RAO KN, 1957, J MOL SPECTROSC, V1, P24