A simple thermal decomposition technique has been executed for the synthesis of cadmium ferrite (CdFe2O4) nanoparticles. With the help of x-ray diffraction; scanning electron microscopy, energy-dispersive x-ray spectroscopy (EDS) and Fourier transform infrared spectroscopy the prepared nanoparticles were identified. The crystal size of the average particles aggregated and was found approximately to be 10-14 nm by means of XRD studies. However, the results of high-resolution transmission electron microscopy (HR-TEM) investigation ensured distinguished nanoparticles, and also the polycrystalline nature of those nanoparticles was confirmed by selected area diffraction (SAED) patterns. The scanning electron microscopy (SEM) images explored a random distribution of grains within the sample. Thin film surface topology of roughness and surface current measurement were studied by atomic force microscopy (TP-AFM, C-AFM). Hence, from the ultraviolet-visible (UV) spectroscopic absorption illustrated significant optical properties. Moreover, the optical energy band gap (E-g) of CdFe2O4 nanoparticle was determined to be 1.74 eV. By studying the variation of dielectric constant and dielectric loss with respect to frequency, the CdFe2O4 nanoparticles electrical properties were analyzed. Analysis in the real and imaginary part of impedance explained their frequency and temperature dependence of the CdFe2O4 nanoparticles. The traditional solution-phase organometallic approach provides an effective way to synthesize high quality hydrophobic semiconductor-CdFe2O4 nanoparticles. Our simple, cost-effective approach is quite general, which is applicable to other nanomaterials, and it utilizes the currently mature in Nano-chemistry. The nanocomposite assemblies' exhibit strong anisotropic optical and electrical properties are open up new possibilities in remarkable applications for optoelectronics in the near future.
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Akamatsu H, 2008, IEEE T MAGN, V44, P2796, DOI 10.1109/TMAG.2008.2001508
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Pontificia Univ Catolica Rio de Janeiro, DCMM, BR-22453900 Rio De Janeiro, BrazilPontificia Univ Catolica Rio de Janeiro, DCMM, BR-22453900 Rio De Janeiro, Brazil
Bueno, Alexandre R.
Gregori, Maria L.
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Inst Pesquisas Marinha, BR-21931090 Rio De Janeiro, BrazilPontificia Univ Catolica Rio de Janeiro, DCMM, BR-22453900 Rio De Janeiro, Brazil
Gregori, Maria L.
Nobrega, Maria C. S.
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Univ Fed Rio de Janeiro Ilha Fundao, PEMM, COPPE, BR-21945970 Rio De Janeiro, BrazilPontificia Univ Catolica Rio de Janeiro, DCMM, BR-22453900 Rio De Janeiro, Brazil
机构:
Pontificia Univ Catolica Rio de Janeiro, DCMM, BR-22453900 Rio De Janeiro, BrazilPontificia Univ Catolica Rio de Janeiro, DCMM, BR-22453900 Rio De Janeiro, Brazil
Bueno, Alexandre R.
Gregori, Maria L.
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Inst Pesquisas Marinha, BR-21931090 Rio De Janeiro, BrazilPontificia Univ Catolica Rio de Janeiro, DCMM, BR-22453900 Rio De Janeiro, Brazil
Gregori, Maria L.
Nobrega, Maria C. S.
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Univ Fed Rio de Janeiro Ilha Fundao, PEMM, COPPE, BR-21945970 Rio De Janeiro, BrazilPontificia Univ Catolica Rio de Janeiro, DCMM, BR-22453900 Rio De Janeiro, Brazil