Phosphine-Free, Heterogeneous Palladium-Catalyzed Atom-Efficient Carbonylative Cross-Coupling of Triarylbismuths with Aryl Iodides: Synthesis of Biaryl Ketones

被引：56

作者：

Hao, Wenyan

Liu, Haiyi

Yin, Lin

Cai, Mingzhong ^{[1
]}

机构：

[1] Jiangxi Normal Univ, Minist Educ, Key Lab Funct Small Organ Mol, Nanchang 330022, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 81卷 / 10期

基金：

中国国家自然科学基金;

关键词：

FRIEDEL-CRAFTS ACYLATION; ONE-POT SYNTHESIS; ARYLBORONIC ACIDS; ACYL CHLORIDES; CARBOXYLIC-ACIDS; BOND FORMATION; IONIC LIQUIDS; HALIDES; CHEMISTRY; ARYLATION;

D O I：

10.1021/acs.joc.6b00570

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel and highly efficient heterogeneous palladium-catalyzed carbonylative cross-coupling of aryl iodides with triarylbismuths has been developed that proceeds smoothly at atmospheric CO pressure and provides a general and powerful tool for the preparation of various valuable biaryl ketones with high atom economy, good to excellent yield, and recyclability of the catalyst. The reaction is the first example of Pd-catalyzed carbonylative cross-coupling for the construction of biaryl ketones using triarylbismuths as substrates.

引用

收藏

页码：4244 / 4251

页数：8

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