Chiral ruthenium complexes as catalysts in enantioselective Diels-Alder reactions. Crystal structure of the Lewis acid dienophile adduct

被引：91

作者：

Carmona, D ^{[1
]}

Cativiela, C

Elipe, S

Lahoz, FJ

Lamata, MP

Pilar, M

de Viu, LR

Oro, LA

Vega, C

Viguri, F

机构：

[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Fac Ciencias,Dept Quim Organ, E-50009 Zaragoza, Spain

[2] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Fac Ciencias,Dept Quim Inorgan, E-50009 Zaragoza, Spain

[3] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Escuela Univ Ingn Tecn Ind,Dept Quim Inorgan, E-50009 Zaragoza, Spain

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 24期

关键词：

D O I：

10.1039/a705605b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

On the basis of spectroscopic and structural studies a full catalytic cycle is proposed for the Diels-Alder reaction between methacrolein and cyclopentadiene when the new chiral aquo-complexes (R-Ru, S-Ru)-[(eta(6)-p-cymene)Ru(PN)(H2O)][SbF6](2) {PN = (3aS, 8aR)-2-(2-diphenyl-phosphinophenyl)-3a,8a-dihydroindane[1,2-d]oxazole} are used as catalysts.

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页码：2351 / 2352

页数：2

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