Virtues and limitations of Pittsburgh green for ozone detection

被引：13

作者：

Beltran, Carlos Castello ^{[1
,2
]}

Palmer, Elliott A. ^{[1
]}

Buckley, Benjamin R. ^{[1
]}

Iza, Felipe ^{[2
]}

机构：

[1] Univ Loughborough, Sch Sci, Dept Chem, Loughborough LE11 3TU, Leics, England

[2] Univ Loughborough, Sch Elect Elect & Syst Engn, Loughborough LE11 3TU, Leics, England

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 09期

基金：

英国工程与自然科学研究理事会; 美国国家科学基金会;

关键词：

LUMINESCENT PROBES; FLUORESCENT;

D O I：

10.1039/c4cc08244c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A recently proposed 2 ',7 '-dichlorofluorescein (DCF)-derived fluorescent probe for the detection of ozone shows good selectivity against a number of reactive oxygen species and good pH stability for biological and environmental applications. It is found, however, that over oxidation of the fluorescent product (Pittsburgh green) can occur. This could render quantitative measurements inaccurate due to a reduction in fluorescence and overlapping fluorescence signals from over oxidation by-products and it requires careful experimental design. Although difficult to assess by fluorescence measurements, the over oxidation can be conveniently monitored by H-1 NMR spectroscopy.

引用

页码：1579 / 1582

页数：4

共 11 条

[1] Fluorescent and luminescent probes for detection of reactive oxygen and nitrogen species [J].

Chen, Xiaoqiang ;

Tian, Xizhe ;

Shin, Injae ;

Yoon, Juyoung .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (09) :4783-4804

[2] Specific fluorogenic probes for ozone in biological and atmospheric samples (vol 1, pg 316, 2009) [J].

Garner, Amanda L. ;

St Croix, Claudette M. ;

Pitt, Bruce R. ;

Leikauf, George D. ;

Ando, Shin ;

Koide, Kazunori .

NATURE CHEMISTRY, 2010, 2 (05) :422-422

[3]

Garner AL, 2009, NAT CHEM, V1, P316, DOI [10.1038/NCHEM.240, 10.1038/nchem.240]

[4] "Turn-on" fluorescent sensing with "reactive" probes [J].

Jun, Mi Eun ;

Roy, Basab ;

Ahn, Kyo Han .

CHEMICAL COMMUNICATIONS, 2011, 47 (27) :7583-7601

[5] Scalable and concise synthesis of dichlorofluorescein derivatives displaying tissue permeation in live zebrafish embryos [J].

Koide, Kazunori ;

Song, Fengling ;

de Groh, Eric D. ;

Garner, Amanda L. ;

Mitchell, Valerie D. ;

Davidson, Lance A. ;

Hukriede, Neil A. .

CHEMBIOCHEM, 2008, 9 (02) :214-218

[6] Amine-Promoted β-Elimination of a β-Aryloxy Aldehyde for Fluorogenic Chemodosimeters [J].

Leslie, Amanda K. ;

Li, Dandan ;

Koide, Kazunori .

JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (16) :6860-6865

[7] A highly sensitive fluorescent sensor for palladium based on the allylic oxidative insertion mechanism [J].

Song, Fengling ;

Garner, Amanda L. ;

Koide, Kazunori .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (41) :12354-+

[8] QUANTITATIVE-DETERMINATION OF AQUEOUS-PHASE OZONE BY CHEMI-LUMINESCENCE USING INDIGO-5,5'-DISULFONATE [J].

TAKEUCHI, K ;

IBUSUKI, T .

ANALYTICAL CHEMISTRY, 1989, 61 (06) :619-623

[9] Fluorescent and luminescent probes for measurement of oxidative and nitrosative species in cells and tissues: Progress, pitfalls, and prospects [J].

Wardman, Peter .

FREE RADICAL BIOLOGY AND MEDICINE, 2007, 43 (07) :995-1022

[10] Evidence for antibody-catalyzed ozone formation in bacterial killing and inflammation [J].

Wentworth, P ;

McDunn, JE ;

Wentworth, AD ;

Takeuchi, C ;

Nieva, J ;

Jones, T ;

Bautista, C ;

Ruedi, JM ;

Gutierrez, A ;

Janda, KD ;

Babior, BM ;

Eschenmoser, A ;

Lerner, RA .

SCIENCE, 2002, 298 (5601) :2195-2199

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