Synthesis of hybrid graphene carbon-coated nanocatalysts

被引:18
作者
Xu, Zhanwei [1 ]
Li, Hejun [1 ]
Cao, Gaoxiang [1 ]
Cao, Zeyuan [1 ]
Zhang, Qinglin [1 ]
Li, Kezhi [1 ]
Hou, Xianghui [2 ]
Li, Wei [1 ]
Cao, Weifeng [1 ]
机构
[1] NW Polytech Univ, CC Composites Res Ctr, State Key Lab Solidificat Proc, Xian 710072, Peoples R China
[2] Univ Nottingham, Dept Mech Mat & Mfg Engn, Nottingham NG7 2RD, England
关键词
OXYGEN REDUCTION; ELECTROCATALYSIS; PHTHALOCYANINE; NANOPARTICLES; ELECTRODES; COBALT; ATOMS; FILMS; CAGE;
D O I
10.1039/c0jm02187c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A hybrid of many few-layer graphene carbon-coated Fe nano particles was produced by pyrolysis of iron tetrapyridinoporphyrazine. It shows high electrochemical activity for oxygen reduction, and exhibits high saturation magnetization and a negligible magnetic hysteresis, suitable for magnetic catalysts and catalyst-support particles.
引用
收藏
页码:8230 / 8232
页数:3
相关论文
共 26 条
[1]   Electrocatalysis at graphite and carbon nanotube modified electrodes: edge-plane sites and tube ends are the reactive sites [J].
Banks, CE ;
Davies, TJ ;
Wildgoose, GG ;
Compton, RG .
CHEMICAL COMMUNICATIONS, 2005, (07) :829-841
[2]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[3]   Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction [J].
Gong, Kuanping ;
Du, Feng ;
Xia, Zhenhai ;
Durstock, Michael ;
Dai, Liming .
SCIENCE, 2009, 323 (5915) :760-764
[4]   Preparation, Characterization, and Surface Modification of Carbon-Encapsulated Nickel Nanoparticles [J].
Huang, Yu'an ;
Xu, Zheng ;
Yang, Yang ;
Tang, Tao ;
Huang, Runsheng ;
Shen, Jianyi .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (16) :6533-6538
[5]   Large-scale pattern growth of graphene films for stretchable transparent electrodes [J].
Kim, Keun Soo ;
Zhao, Yue ;
Jang, Houk ;
Lee, Sang Yoon ;
Kim, Jong Min ;
Kim, Kwang S. ;
Ahn, Jong-Hyun ;
Kim, Philip ;
Choi, Jae-Young ;
Hong, Byung Hee .
NATURE, 2009, 457 (7230) :706-710
[6]   Magnetic characterization of Fe-nanoparticles encapsulated single-walled carbonnanotubes [J].
Li, Yongfeng ;
Kaneko, Toshiro ;
Ogawa, Tomoyuki ;
Takahashi, Migaku ;
Hatakeyama, Rikizo .
CHEMICAL COMMUNICATIONS, 2007, (03) :254-256
[7]   Preparation and characteristics of carbon nanotubes filled with cobalt [J].
Liu, SW ;
Zhu, JJ ;
Mastai, Y ;
Felner, I ;
Gedanken, A .
CHEMISTRY OF MATERIALS, 2000, 12 (08) :2205-2211
[8]   The nano-forms of carbon [J].
Luis Delgado, Juan ;
Angeles Herranz, M. ;
Martin, Nazario .
JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (13) :1417-1426
[9]   A simple direct borohydride fuel cell with a cobalt phthalocyanine catalyzed cathode [J].
Ma, Jinfu ;
Liu, Yongning ;
Zhang, Peng ;
Wang, Jin .
ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (01) :100-102
[10]   Direct preparation of carbon nanofiber electrodes via pyrolysis of iron(II) phthalocyanine: Electrocatalytic aspects for oxygen reduction [J].
Maldonado, S ;
Stevenson, KJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (31) :11375-11383