Synthesis of linear oligo-TTFs and their [2]rotaxanes with cyclobis(paraquat-p-phenylene)

被引:21
作者
Damgaard, D
Nielsen, MB
Lau, J
Jensen, KB
Zubarev, R
Levillain, E
Becher, J
机构
[1] Odense Univ, Dept Chem, Univ So Denmark, DK-5230 Odense M, Denmark
[2] IMMO, CNRS, UMR 6501, F-49045 Angers, France
关键词
D O I
10.1039/b001868f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Two linear oligo-TTFs were synthesised employing a stepwise strategy involving two different thiolate protecting groups. These linear TTFs were incorporated into donor-acceptor rotaxanes with the cyclic acceptor, cyclobis(paraquat-p-phenylene). Moreover, a prototype rotaxane based on a bis(pyrrolo)-TTF was prepared and studied.
引用
收藏
页码:2249 / 2258
页数:10
相关论文
共 30 条
  • [1] OLIGOMERIC TETRATHIAFULVALENES - EXTENDED DONORS FOR INCREASING THE DIMENSIONALITY OF ELECTRICAL-CONDUCTION
    ADAM, M
    MULLEN, K
    [J]. ADVANCED MATERIALS, 1994, 6 (06) : 439 - 459
  • [2] Toward controllable molecular shuttles
    Anelli, PL
    Asakawa, M
    Ashton, PR
    Bissell, RA
    Clavier, G
    Gorski, R
    Kaifer, AE
    Langford, SJ
    Mattersteig, G
    Menzer, S
    Philp, D
    Slawin, AMZ
    Spencer, N
    Stoddart, JF
    Tolley, MS
    Williams, DJ
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (07) : 1113 - 1135
  • [3] A three-pole supramolecular switch
    Ashton, PR
    Balzani, V
    Becher, J
    Credi, A
    Fyfe, MCT
    Mattersteig, G
    Menzer, S
    Nielsen, MB
    Raymo, FM
    Stoddart, JF
    Venturi, M
    Williams, DJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (16) : 3951 - 3957
  • [4] Ashton PR, 1996, CHEM-EUR J, V2, P729
  • [5] Molecular machines
    Balzani, V
    Gómez-López, M
    Stoddart, JF
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (07) : 405 - 414
  • [6] 2-MONO OR 2,3-BIS(HYDROXYMETHYL)-6,7-ETHYLENEDITHIO-TETRATHIAFULVALENES - NEW POTENTIAL PRECURSORS OF ORGANIC METALS ENDOWED WITH HYDROGEN-BONDS
    BLANCHARD, P
    SALLE, M
    DUGUAY, G
    JUBAULT, M
    GORGUES, A
    [J]. TETRAHEDRON LETTERS, 1992, 33 (19) : 2685 - 2688
  • [7] Electronically configurable molecular-based logic gates
    Collier, CP
    Wong, EW
    Belohradsky, M
    Raymo, FM
    Stoddart, JF
    Kuekes, PJ
    Williams, RS
    Heath, JR
    [J]. SCIENCE, 1999, 285 (5426) : 391 - 394
  • [8] A redox-active tetrathiafulvalene [2]pseudorotaxane: Spectroelectrochemical and cyclic voltammetric studies of the highly-reversible complexation/decomplexation process
    Devonport, W
    Blower, MA
    Bryce, MR
    Goldenberg, LM
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (04) : 885 - 887
  • [9] A STRAIGHTFORWARD APPROACH TO THE SYNTHESIS OF UNSYMMETRICAL TETRATHIOALKYL TETRATHIAFULVALENE DERIVATIVES
    GEMMELL, C
    KILBURN, JD
    UECK, H
    UNDERHILL, AE
    [J]. TETRAHEDRON LETTERS, 1992, 33 (27) : 3923 - 3926
  • [10] SYNTHESIS AND PRELIMINARY CHARACTERIZATION OF SOME POLYESTER ROTAXANES
    GIBSON, HW
    LIU, S
    LECAVALIER, P
    WU, C
    SHEN, YX
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (03) : 852 - 874