On protons, iron and the high-pressure behavior of ringwoodite

被引:37
|
作者
Kleppe, AK
Jephcoat, AP
Smyth, JR
Frost, DJ
机构
[1] Univ Oxford, Dept Earth Sci, Oxford OX1 3PR, England
[2] Univ Colorado, Dept Geol Sci, Boulder, CO 80309 USA
[3] Univ Bayreuth, Bayer Geoinst, D-95440 Bayreuth, Germany
关键词
D O I
10.1029/2002GL015276
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
Raman spectra of a single crystal of hydrous Fo(89)-ringwoodite have been measured in a diamond-anvil cell at room temperature to 60 GPa. Strong peaks corresponding to asymmetric and symmetric stretching vibrations of the SiO4 tetrahedra are observed at 796 and 841 cm(-1) respectively. Additional bands occur in the range 709-939 and 100-250 cm(-1). The SiO4 stretching modes of the spinel structure shift continuously up to 60 GPa. Near 40 GPa new Raman bands emerge in the region 550-680 cm(-1) gaining intensity to the maximum pressure, a change that is reversible on pressure release. This pressure-induced modification in the structure appears to be related to structural complexity generated by both Fe and proton substitution.
引用
收藏
页码:17 / 1
页数:4
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