Scaling and criticality of the Manning transition

被引:4
|
作者
Cha, Minryeong [1 ]
Yi, Juyeon [2 ]
Kim, Yong Woon [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Grad Sch Nanosci & Technol, Deajeon 34141, South Korea
[2] Pusan Natl Univ, Dept Phys, Busan 46241, South Korea
来源
EUROPEAN PHYSICAL JOURNAL E | 2017年 / 40卷 / 08期
关键词
POISSON-BOLTZMANN; COUNTERION CONDENSATION; POLYELECTROLYTE SOLUTIONS; LIMITING LAWS; ELECTROLYTES; SIMULATIONS; DNA;
D O I
10.1140/epje/i2017-11559-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We consider a system consisting of a charged cylinder in the presence of neutralizing counterions. This system is well known to exhibit the Manning transition of counterion condensation onto the charged cylinder. We study the criticality and the scaling properties of the Manning transition, analyzing involved thermodynamic quantities such as condensed fraction, its fluctuation, and heat capacity. Through the Monte Carlo simulations and finite-size scaling analysis, we find that near the transition point the examined quantities exhibit scale-invariant behaviors with specific exponents, which provides an evidence that the Manning transition is a critical phenomenon having a scale-invariant property, analogous to bulk phase transitions. Furthermore, we numerically confirm that such scaling properties are not affected by the coupling strength.
引用
收藏
页数:7
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