Development of porous carbon foam polymer electrolyte membrane fuel cell

被引:38
作者
Kim, Jin [1 ,2 ]
Cunningham, Nicolas [1 ,2 ]
机构
[1] Royal Mil Coll Canada, Dept Chem & Chem Engn, Kingston, ON K7K 7B4, Canada
[2] Queens RMC Fuel Cell Res Ctr, Kingston, ON K7L 5L9, Canada
关键词
PEMFC; Foam fuel cell; RVC foam; Porous electrode; Cathode flow-field; GAS-DIFFUSION LAYER; FLOW-FIELD; BIPOLAR/END PLATES; VOLTAGE DEGRADATION; TRANSPORT PHENOMENA; METAL FOAM; PERFORMANCE; PEMFC; CATHODE; ISSUES;
D O I
10.1016/j.jpowsour.2009.10.053
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In order to prove the feasibility of using porous carbon foam material in a polymer electrolyte membrane fuel cell (PEMFC), a single PEMFC is constructed with a piece of 80PPI (pores per linear inch) Reticulated Vitreous Carbon (RVC) foam at a thickness of 3.5 mm employed in the cathode flow-field. The cell performance of such design is compared with that of a conventional fuel cell with serpentine channel design in the cathode and anode flow-fields. Experimental results show that the RVC foam fuel cell not only produces comparative power density to, but also offers interesting benefits over the conventional fuel cell. A 250 h long term test conducted on a RVC foam fuel cell shows that the durability and performance stability of the material is deemed to be acceptable. Furthermore, a parametric study is conducted on single RVC foam fuel cells. Effect of geometrical and material parameters of the RVC foam such as PPI and thickness and operating conditions such as pressure, temperature, and stoichiometric ratio of the reactant gases on the cell performance is experimentally investigated in detail. The single cell with the 80PPI RVC foam exhibits the best performance, especially if the thinnest foam (3.5 mm) is used. The cell performance improves with increasing the operating gauge pressure from 0 kPa to 80 kPa and the operating temperature from 40 degrees C to 60 degrees C, but deteriorates as it further increases to 80 degrees C. The cell performance improves as the stoichiometric ratio of air increases from 1.5 to 4.5; however, the improvement becomes marginal when it is raised above 3.0. On the other hand, changing the stoichiometric ratio of hydrogen does not have a significant impact on the cell performance. Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:2291 / 2300
页数:10
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