Assembly of metal-organic frameworks (MOFs) based on indium-trimer building blocks: A porous MOF with soc topology and high hydrogen storage

被引：662
作者：
Liu, Yunling
Eubank, Jarrod F.
Cairns, Amy J.
Eckert, Juergen
Kravtsov, Victor Ch.
Luebke, Ryan
Eddaoudi, Mohamed
机构：
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat, Changchun 130012, Peoples R China
[3] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
[4] Los Alamos Natl Lab, LANSCE LC, Los Alamos, NM 87545 USA
[5] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 18期
关键词：
hydrogen storage; indium; metal-organic frameworks; molecular building blocks; porous materials;
D O I：
10.1002/anie.200604306
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) The key to soc-cess: The trimer building block [In 3O(CO2)6] and a tetracarboxylate organic linker assemble into a novel porous metal-organic framework (see picture; In green, C gray, N blue, O red; cavity: yellow sphere) having an unprecedented soc topology (soc = square-octahedron) and high H2 uptake. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：3278 / 3283
页数：6
相关论文
共 66 条
[1]   The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].
Allen, FH .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388
[2]  
[Anonymous], 2004, Angew. Chem, V116, P2388, DOI DOI 10.1016/j.jechem.2020.01.001
[3]  
[Anonymous], UNPUB
[4]   [VIII(H2O)]3O(O2CC6H4CO2)3•(Cl, 9H2O) (MIL-59):: a rare example of vanadocarboxylate with a magnetically frustrated three-dimensional hybrid framework [J].
Barthelet, K ;
Riou, D ;
Férey, G .
CHEMICAL COMMUNICATIONS, 2002, (14) :1492-1493
[5]   Single-metal-ion-based molecular building blocks (MBBs) approach to the design and synthesis of metal-organic assemblies [J].
Brant, Jacilynn A. ;
Liu, Yunling ;
Sava, Dorina F. ;
Beauchamp, Derek ;
Eddaoudi, Mohamed .
JOURNAL OF MOLECULAR STRUCTURE, 2006, 796 (1-3) :160-164
[6]   Quantum rotation of hydrogen in single-wall carbon nanotubes [J].
Brown, CM ;
Yildirim, T ;
Neumann, DA ;
Heben, MJ ;
Gennett, T ;
Dillon, AC ;
Alleman, JL ;
Fischer, JE .
CHEMICAL PHYSICS LETTERS, 2000, 329 (3-4) :311-316
[7]  
Cheetham A. K., 1999, ANGEW CHEM, V111, P3466
[8]  
Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO
[9]  
2-U
[10]   Porous, crystalline, covalent organic frameworks [J].
Côté, AP ;
Benin, AI ;
Ockwig, NW ;
O'Keeffe, M ;
Matzger, AJ ;
Yaghi, OM .
SCIENCE, 2005, 310 (5751) :1166-1170
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