Nano ZnO, Cu-doped ZnO, and Ag-doped ZnO assisted generation of light from imidazole

被引:23
作者
Jayabharathi, J. [1 ]
Karunakaran, C. [1 ]
Kalaiarasi, V. [1 ]
Ramanathan, P. [1 ]
机构
[1] Annamalai Univ, Dept Chem, Annamalainagar 608002, Tamil Nadu, India
关键词
SEM; EDX; Fluorescence; ZnO; XRD; DRS; CORE-SHELL NANOPARTICLES; PHOTOLUMINESCENCE; EMISSION; ELECTRON; OXYGEN; DOTS;
D O I
10.1016/j.jphotochem.2014.09.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A sensitive 2-(4-methoxyphenyl)-1-(naphthalene-1-yl)-4,5-diphenyl-1H-imidazole (MNDI) fluorescent sensor for nanoparticulate ZnO has been designed and synthesized. The nanocrystalline ZnO, Cu-doped ZnO, and Ag-doped ZnO have been synthesised by sol-gel method and characterized by powder X-ray diffraction, scanning electron microscopy(SEM), UV-vis diffuse reflectance, photoluminescence and life time spectral studies. All the synthesized nanoparticles display violet emission due to charge carrier-recombination. The synthesized sensor emission is enhanced by nanocrystalline pristine ZnO but is suppressed by Cu-doped ZnO and Ag-doped ZnO nanoparticles. The suppression of fluorescence is more by copper than by silver doping. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 10
页数:10
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