共 329 条
Polyoxometalates (POMs): from electroactive clusters to energy materials
被引:294
作者:
Horn, Michael R.
[1
,4
]
Singh, Amandeep
[1
,4
]
Alomari, Suaad
[1
]
Goberna-Ferron, Sara
[2
]
Benages-Vilau, Raul
[2
]
Chodankar, Nilesh
[3
]
Motta, Nunzio
[1
,4
]
Ostrikov, Kostya
[1
,4
]
MacLeod, Jennifer
[1
,4
]
Sonar, Prashant
[1
,4
]
Gomez-Romero, Pedro
[2
,5
]
Dubal, Deepak
[1
,4
]
机构:
[1] Queensland Univ Technol QUT, Sch Chem & Phys, 2 George St, Brisbane, Qld 4000, Australia
[2] ICN2 CSIC BIST, Catalan Inst Nanosci & Nanotechnol, Campus UAB, E-08193 Barcelona, Spain
[3] Dongguk Univ Seoul, Dept Energy & Mat Engn, Seoul 04620, South Korea
[4] Queensland Univ Technol QUT, Ctr Mat Sci, 2 George St, Brisbane, Qld 4000, Australia
[5] CSIC, Madrid, Spain
基金:
澳大利亚研究理事会;
欧盟地平线“2020”;
关键词:
DRIVEN WATER-OXIDATION;
METAL-ORGANIC FRAMEWORKS;
ELECTROCATALYTIC OXYGEN REDUCTION;
GRAPHITIC CARBON NITRIDE;
REDOX FLOW BATTERIES;
LITHIUM ION BATTERY;
HIGH-PERFORMANCE;
HYBRID MATERIALS;
COBALT-POLYOXOMETALATE;
HYDROGEN EVOLUTION;
D O I:
10.1039/d0ee03407j
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Polyoxometalates (POMs) represent a class of nanomaterials, which hold enormous promise for a range of energy-related applications. Their promise is owing to their "special'' structure that gives POMs a truly unique ability to control redox reactions in energy conversion and storage. One such amazing capability is their large number of redox active sites that arises from the complex three-dimensional cluster of metal-oxide ions linked together by oxygen atoms. Here, a critical review on how POMs emerged from being molecular clusters for fundamental studies, to next-generation materials for energy applications is provided. We highlight how exploiting the versatility and activity of these molecules can lead to improved performance in energy devices such as supercapacitors and batteries, and in energy catalyst applications. The potential of POMs across numerous fields is systematically outlined by investigating structure-property-performance relationships and the determinant factors for energy systems. Finally, the challenges and opportunities for this class of materials with respect to addressing our pressing energy-related concerns are identified.
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页码:1652 / 1700
页数:49
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