Flow-induced-crystallization: tailoring host-guest supramolecular co-assemblies at the liquid-solid interface

被引：8

作者：

Hu, Yi ^{[1
]}

Zeng, Xingming ^{[1
]}

Sahare, Sanjay ^{[1
]}

Xie, Rong-Bin ^{[1
]}

Lee, Shern-Long ^{[1
]}

机构：

[1] Shenzhen Univ, Inst Adv Study, Shenzhen 518060, Peoples R China

来源：

NANOSCALE ADVANCES | 2022年 / 4卷 / 17期

关键词：

MOLECULAR ASSEMBLIES; 2D; FULLERENES; MONOLAYERS; ALIGNMENT; NETWORK;

D O I：

10.1039/d2na00160h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here, we report that using the method of simply contacting a sample solution droplet with a piece of tissue paper can create a solvent flow (capillary force). During this process, the dynamics and solvent removal can promote the formation and stabilization of a meta-stable linear quasi-crystal composed of p-terphenyl-3,5,3 ',5 '-tetracarboxylic acid (TPTC) molecules, which would otherwise pack into thermodynamically favored random tiling. The tailored quasi-crystal (linear) template allows atop it higher-efficiency accommodation of fullerene molecules (C-60) from 40.1% to 97.5%, compared with that obtained in the random-tiling (porous) case. Overall, the result of this study presents an unusual yet remarkably simple strategy for tailoring complex host-guest supramolecular systems at the liquid-solid interface.

引用

页码：3524 / 3530

页数：8

共 28 条

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