A new chiral coordination polymer based on [Fe(CN)6]4-, Cu2+ cations, and (2S, 3S)-1,2,3,4-tetraaminobutane:: synthesis, structure, and ESR spectra

被引：1

作者：

Mironov, Yu. V.

Nadolinny, V. A.

Naumov, D. Yu.

Hegetschweiler, K.

Fedorov, V. E.

机构：

[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Univ Saarland, Inst Inorgan Chem, D-6600 Saarbrucken, Germany

[3] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2007年 / 56卷 / 03期

关键词：

potassium hexacyanoferrate; chiral coordination polymers; polydentate amines; crystal structure;

D O I：

10.1007/s11172-007-0073-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new chiral coordination polymer [{Cu(NH3)(threo-tab)}(2)Fe(CN)(6)]center dot 8H(2)O was synthesized by the reaction of an aqueous solution of potassium hexacyanoferrate with an ammonia solution of copper(II) chloride and (2S,3S)-1,2,3,4-tetraaminobutane (threo-tab). The structure of the coordination polymer was established by X-ray diffraction. The ESR spectra of this compound were measured for a powder and a single crystal.

引用

页码：452 / 455

页数：4

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