Time-resolved luminescence quenching in thin films of perylene-tetracarboxylic-dianhydride

被引:13
作者
Schüppel, R [1 ]
Dienel, T [1 ]
Leo, K [1 ]
Hoffmann, M [1 ]
机构
[1] Tech Univ Dresden, Inst Angew Photophys, D-01062 Dresden, Germany
关键词
PTCDA (perylene-3,4,9,10-tetracarboxylic-dianhydride); organic thin films; time-resolved luminescence; luminescence quenching; exciton diffusion;
D O I
10.1016/j.jlumin.2004.08.026
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We present luminescence quenching experiments and determine the exciton diffusion length in polycrystalline thin films of PTCDA (perylene-3,4,9,10-tetracarboxylic-dianhydride). From an analysis of time-resolved experiments, we can distinguish between exciton transport during an ultra-fast initial relaxation phase and transport in the long-living emitting states. The temperature dependence of the exciton diffusion constant in the emitting states indicates thermally activated hopping. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:309 / 314
页数:6
相关论文
共 13 条
[1]  
Agranovich V.M., 1982, Electronic Excitation Energy Transfer in Condensed Matter
[2]  
ENGEL E, IN PRESS
[3]   Long-range singlet energy transfer in perylene bis(phenethylimide) films [J].
Gregg, BA ;
Sprague, J ;
Peterson, MW .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (27) :5362-5369
[4]   Vibronic structure of PTCDA stacks: the exciton-phonon-charge-transfer dimer [J].
Hennessy, MH ;
Soos, ZG ;
Pascal, RA ;
Girlando, A .
CHEMICAL PHYSICS, 1999, 245 (1-3) :199-212
[5]  
Hoffmann M., 2002, Nonlinear Optics, Principles, Materials, Phenomena, and Devices, V29, P227, DOI 10.1080/1058726021000044514
[6]   Optical absorption spectra of the Holstein molecular crystal for weak and intermediate electronic coupling [J].
Hoffmann, M ;
Soos, ZG .
PHYSICAL REVIEW B, 2002, 66 (02) :243051-2430518
[7]   THEORY OF EXCITON MIGRATION EXPERIMENTS WITH IMPERFECTLY ABSORBING END DETECTORS [J].
KENKRE, VM ;
WONG, YM .
PHYSICAL REVIEW B, 1980, 22 (12) :5716-5722
[8]   Time-resolved photoluminescence study of excitons in α-PTCDA as a function of temperature -: art. no. 155201 [J].
Kobitski, AY ;
Scholz, R ;
Zahn, DRT ;
Wagner, HP .
PHYSICAL REVIEW B, 2003, 68 (15)
[9]   Low-temperature time-resolved photoluminescence characterization of 3,4,9,10-perylene tetracarboxylic dianhydride crystals [J].
Kobitski, AY ;
Scholz, R ;
Vragovic, I ;
Wagner, HP ;
Zahn, DRT .
PHYSICAL REVIEW B, 2002, 66 (15) :1-4
[10]   Two-component optical spectra in thin PTCDA films due to the coexistence of α- and β-phase [J].
Leonhardt, M ;
Mager, O ;
Port, H .
CHEMICAL PHYSICS LETTERS, 1999, 313 (1-2) :24-30