Cyclopalladated imine catalysts in Heck arylation: search for the catalytic species

被引：123

作者：

Nowotny, M ^{[1
]}

Hanefeld, U ^{[1
]}

van Koningsveld, H ^{[1
]}

Maschmeyer, T ^{[1
]}

机构：

[1] Delft Univ Technol, Lab Appl Organ Chem & Catalysis, NL-2628 BL Delft, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 19期

关键词：

D O I：

10.1039/b004502k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The application of the new cyclopalladated imine complexes of the Milstein-type 1d, 2a and 2b and the immobilised derivative 2c in the Heck reaction has provided evidence that these complexes are unstable and the active species is metallic palladium.

引用

页码：1877 / 1878

页数：2

共 14 条

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