Non-mercury catalytic acetylene hydrochlorination over a NH4F-urea-modified Pd/HY catalyst for vinyl chloride monomer production

被引:35
作者
Wang, Lu
Wang, Feng [1 ]
Wang, Jide
机构
[1] Xinjiang Univ, Minist Educ, Key Lab Oil & Gas Fine Chem, Urumqi 830046, Xinjiang, Peoples R China
基金
中国国家自然科学基金;
关键词
STABILITY; ZEOLITES;
D O I
10.1039/c5nj03338a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A Pd/HY zeolite catalyst modified with ammonium fluoride and urea (Pd/NH4F-urea-HY) was efficiently applied in an acetylene hydrochlorination reaction. It exhibited an enhanced catalytic performance compared to the untreated Pd/HY catalyst, which was attributed to the presence of ammonium fluoride and urea partly inhibiting carbon deposition and Pd2+ reduction.
引用
收藏
页码:3019 / 3023
页数:5
相关论文
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