Dynamic supramacromolecular self-assembly: deformable polymer fabricated nanostructures through a host-controlled approach

被引：29

作者：

Yan, Qiang ^{[1
]}

Yuan, Jinying ^{[1
]}

Kang, Yan ^{[1
]}

Yin, Yingwu ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China

来源：

POLYMER CHEMISTRY | 2010年 / 1卷 / 04期

基金：

中国国家自然科学基金;

关键词：

BLOCK-COPOLYMER; ALPHA-CYCLODEXTRIN; COMPLEX-FORMATION; VESICLES; MICELLES; DIBLOCK; POLY(EPSILON-CAPROLACTONE); MICELLIZATION; ORGANIZATION;

D O I：

10.1039/c0py00024h

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Host molecules (alpha-CD) hierarchically thread onto the double grafts of the comb-copolymer EC-g-PCL-b-PEO from the outer block to the inner block in aqueous solution. Adjusting the molar ratio between alpha-CD and copolymer can induce these supramacromolecular complexes to dynamically and reversibly self-tune their fabrication from micelles (0-D) to cylinders (1-D) to vesicles (3-D) to sheets (2-D) like "living" assemblies.

引用

页码：423 / 425

页数：3

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