Sodium-Ion Conducting Solid Electrolytes in the Na2S-In2S3 System

被引：9
作者：
Motohashi, Kota [1 ,2 ]
Nasu, Akira [1 ]
Kimura, Takuya [1 ]
Hotehama, Chie [1 ]
Sakuda, Atsushi [1 ,2 ]
Tatsumisago, Masahiro [1 ,2 ]
Hayashi, Akitoshi [1 ,2 ]
机构：
[1] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Naka Ku, 1-1 Gakuen Cho, Sakai, Osaka 5998531, Japan
[2] Osaka Metropolitan Univ, Osaka, Japan
来源：
ELECTROCHEMISTRY | 2022年 / 90卷 / 06期
关键词：
Solid Electrolyte; Na Ion Conductor; Sulfide Electrolyte; All-solid-state Na Battery; 3-DIMENSIONAL VISUALIZATION; SUPERIONIC CONDUCTOR; NA3SBS4; LI6PS5X; GLASS; CL;
D O I：
10.5796/electrochemistry.22-00037
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The development of solid electrolytes is necessary for practical applications of all-solid-state Na-ion batteries. In this study, we systematically developed sulfide Na-ion conductors with central In cations, prepared by solid-state reaction and mechanochemical methods. Thermodynamically stable crystals of Na5InS4 and NaInS2 were obtained by the solid-state reaction method, whereas amorphous and/or metastable phases were produced by the mechanochemical method. Two new metastable phases, Na5InS4 and NaInS2, are expected to be examined in the future as end-members of sulfide Na-ion conductors with central In cations. (C) The Author(s) 2022. Published by ECSJ.
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页数：5
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