Synthetic studies on brevetoxin-B. Part 1: Stereoselective synthesis of the ABC-ring system

被引：29

作者：

Matsuo, G ^{[1
]}

Matsukura, H ^{[1
]}

Hori, N ^{[1
]}

Nakata, T ^{[1
]}

机构：

[1] RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 40期

关键词：

brevetoxin-B; endo-cyclization; olefin metathesis; radical cyclization; samarium diiodide;

D O I：

10.1016/S0040-4039(00)01341-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The ABC-ring system of brevetoxin-B was stereoselectively synthesized based on the 6-endo-cyclization of a hydroxy methylepoxide, ring-closing olefin metathesis and SmI2-induced reductive intramolecular cyclization. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：7673 / 7676

页数：4

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