A hybrid intumescent fire retardant coating from cake- and eggshell-type IFRC

被引:30
作者
Chou, Chuen-Shii [1 ]
Lin, Sheau-Horng [2 ]
Wang, Chin-I [1 ]
Liu, Kuan-Hung [1 ]
机构
[1] Natl Pingtung Univ Sci & Technol, Dept Mech Engn, Powder Technol R&D Lab, Pingtung 912, Taiwan
[2] Natl Pingtung Univ Sci & Technol, Dept Wood Sci & Design, Pingtung 912, Taiwan
关键词
Flame retardant; Intumescent fire retardant coating; Fire protection; Carbon source; RESISTANCE; MECHANISM;
D O I
10.1016/j.powtec.2009.11.004
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this study the applicability of name retardant mixed with a carbon source (such as pentaerythritol) for the intumescent fire retardant coating (IFRC) daubed on the top of a piece of plywood was investigated. There are three kinds of flame retardants used in this study: ( 1) artificial mesophase graphite powder (MGP), (2) sericite (Al-4(OH)(4)(KAlSi3O10)(2)), and (3) graphite. The desirable sizes of graphite, MGP and sericite were obtained by sieving. The graphite, MGP and sericite were characterized Using a scanning electron microscope (SEM) and an energy dispersive spectrum (EDS). The IFRC, which consisted of 19.8% of name retardant (or flame retardant mixed with carbon source), 15% of dehydrate agent, 18% of foaming agent, 7.2% of resin binder, and 40% of solvent, was prepared and daubed oil the top of plywood. The fire protection capability of IFRC was tested using a flammability 45 degrees tester. A conventional IFRC (with the carbon source) was also prepared to study the effect of adding the mixture of flame retardant and carbon source oil the fire protection capability of IFRC. The microstructures of the conventional IFRC, the IFRC with flame retardant, and the hybrid IFRC (with flame retardant and carbon source) were inferred and demonstrated using SEM micrographs of the cross-section of three kinds of burnt IFRC. Most interestingly, the fire protection capability of the hybrid IFRC exceeds that of the conventional IFRC even though the percentage of carbon in the burnt hybrid IFRC is less than that in the burnt conventional IFRC. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:149 / 156
页数:8
相关论文
共 16 条
  • [1] 4A zeolite synergistic agent in new flame retardant intumescent formulations of polyethylenic polymers - Study of the effect of the constituent monomers
    Bourbigot, S
    LeBras, M
    Delobel, R
    Breant, P
    Tremillon, JM
    [J]. POLYMER DEGRADATION AND STABILITY, 1996, 54 (2-3) : 275 - 287
  • [2] Camino G., 1998, Fire retardancy of polymers: the use of intumescence, Ed, P48, DOI DOI 10.1533/9781845698584.2.48
  • [3] Preparation and characterization of the intumescent fire retardant coating with a new flame retardant
    Chou, Chuen-Shii
    Lin, Sheau-Horng
    Wang, Chin-I
    [J]. ADVANCED POWDER TECHNOLOGY, 2009, 20 (02) : 169 - 176
  • [4] *CNS, 1981, 7614 CNS
  • [5] Preparation and physical properties of flame retardant acrylic resin containing nano-sized aluminum hydroxide
    Daimatsu, Kazuki
    Sugimoto, Hideki
    Kato, Yasunori
    Nakanishi, Eiji
    Inomata, Katsuhiro
    Amekawa, Yoshihide
    Takemura, Kazuki
    [J]. POLYMER DEGRADATION AND STABILITY, 2007, 92 (08) : 1433 - 1438
  • [6] Intumescence in fire retardancy of lignocellulosic panels
    Grexa, O
    Poutch, F
    Manikova, D
    Martvonova, H
    Bartekova, A
    [J]. POLYMER DEGRADATION AND STABILITY, 2003, 82 (02) : 373 - 377
  • [7] Study on preparation and fire-retardant mechanism analysis of intumescent flame-retardant coatings
    Gu, Jun-wei
    Zhang, Guang-cheng
    Dong, Shan-lai
    Zhang, Qiu-yu
    Kong, Jie
    [J]. SURFACE & COATINGS TECHNOLOGY, 2007, 201 (18) : 7835 - 7841
  • [8] HWANG JC, 1986, COATING ENG, V68, P51
  • [9] *JIS, 1966, A1322 JIS
  • [10] Enhanced gene delivery to HER-2-overexpressing breast cancer cells by modified immunolipoplexes conjugated with the anti-HER-2 antibody
    Lee, CH
    Hsiao, M
    Tseng, YL
    Chang, FH
    [J]. JOURNAL OF BIOMEDICAL SCIENCE, 2003, 10 (03) : 337 - 344