Highly efficient aerobic oxidation of oximes to carbonyl compounds catalyzed by metalloporphyrins in the presence of benzaldehyde

被引：51
|
作者：
Zhou, Xian-Tai [1 ]
Yuan, Qiu-Lan [2 ]
Ji, Hong-Bing [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China
[2] Longyan Univ, Sch Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 04期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
Oxime; Carbonyl compound; Oxidation; Metalloporphyrins; MESO-TETRAPHENYLPORPHYRIN CHLORIDE; NITRIC-OXIDE SYNTHASE; MOLECULAR-OXYGEN; PYRIDINIUM FLUOROCHROMATE; POTASSIUM-PERMANGANATE; CYCLOHEXANE OXIDATION; SELECTIVE OXIDATION; FACILE DEPROTECTION; BIOMIMETIC MODELS; CHROMIUM TRIOXIDE;
D O I：
10.1016/j.tetlet.2009.11.078
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Highly efficient oxidation of oximes to carbonyl compounds by molecular oxygen with benzaldehyde as an oxygen acceptor in the presence of metalloporphyrins has been reported. The simple structural manganese porphyrin showed an excellent activity for the oxidative deoximation reactions of various oximes. Moreover, different factors influencing oximes oxidation, that is, catalyst, solvent, and temperature, have been investigated. A possible mechanism for the deoximation reaction has been proposed. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：613 / 617
页数：5
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