Synthesis of new adsorbent copper(II) terephthalate

被引：160

作者：

Mori, W ^{[1
]}

Inoue, F

Yoshida, K

Nakayama, H

Takamizawa, S

Kishita, M

机构：

[1] Kanagawa Univ, Fac Sci, Dept Chem, Kanagawa 25912, Japan

[2] Osaka Univ, Grad Sch Sci, Dept Chem, Osaka 560, Japan

[3] Kobe Pharmaceut Univ, Kobe, Hyogo 658, Japan

来源：

CHEMISTRY LETTERS | 1997年 / 12期

关键词：

D O I：

10.1246/cl.1997.1219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper(II) terephthalate absorbs a large amount of gases such as N-2, Ar, O-2, and Xe. The maximum amounts of absorption of gases were 1.8, 1.9, 2.2, and 0.9 mole per one mole of the copper(II) salt for N-2, Ar, O-2, and Xe, respectively, indicating that the gases were not adsorbed on the surface but occluded within the solid. The porous structure of copper(II) terephthalate, in which the gas is occluded, is deduced from the temperature dependence of magnetic susceptibilities and the linear structure of terephthalate.

引用

页码：1219 / 1220

页数：2

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