Photocatalytic Hydrogen Evolution Using ZnS Particles and LEDs

被引：3
作者：
Maass, Mona Christin [1 ]
Tasch, Alexander [1 ]
Jooss, Christian [2 ]
Waitz, Thomas [1 ]
机构：
[1] Univ Gottingen, Inst Inorgan Chem, Chem Educ Dept, D-37077 Gottingen, Germany
[2] Univ Gottingen, Inst Mat Phys, D-37077 Gottingen, Germany
来源：
JOURNAL OF CHEMICAL EDUCATION | 2022年 / 99卷 / 05期
关键词：
High School; Introductory Chemistry; First-Year Undergraduate; General; Laboratory Instruction; Public Understanding; Outreach; Hands-On Learning; Photochemistry; Semiconductors; PHOTOCATALYSIS; REMEDIATION; DEGRADATION; STUDENTS; LIGHT; WATER; DYE;
D O I：
10.1021/acs.jchemed.1c01157
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydrogen is a sustainable and climate-friendly storage forrenewable energies and can directly be generated from sunlight, e.g., byphotocatalytic water splitting. This article presents the photocatalytichydrogen evolution using LED irradiation of an aqueous ZnS particledispersion with Na2S and Na2SO3as sacrificial reagents. In contrast topreviously published photocatalytic hydrogen production experiments foreducational purposes, this experiment is safer and more environmentallyfriendly and can therefore be performed by students in school laboratoriesor in regular K-12 chemistry classes using a self-constructed low-costsetup. In addition, digital competences are fostered since the holder of theLED is constructed with a 3D printer and the formed hydrogen isdetected with an Arduino hydrogen sensor.
引用
收藏
页码：2086 / 2092
页数：7
相关论文
共 25 条
  • [1] [Anonymous], LEIBNIZ I SCI MATH E
  • [2] [Anonymous], GASSENSOR JOY IT
  • [3] Involving Students in a Collaborative Project To Help Discover Inexpensive, Stable Materials for Solar Photoelectrolysis
    Anunson, Paige N.
    Winlder, Gates R.
    Winkler, Jay R.
    Parkinson, Bruce A.
    Christus, Jennifer D. Schuttlefield
    [J]. JOURNAL OF CHEMICAL EDUCATION, 2013, 90 (10) : 1333 - 1340
  • [4] Bumpus JA, 1999, J CHEM EDUC, V76, P1680
  • [5] A simple parallel photochemical reactor for photodecomposition studies
    Chen, XB
    Halasz, SM
    Giles, EC
    Mankus, JV
    Johnson, JC
    Burda, C
    [J]. JOURNAL OF CHEMICAL EDUCATION, 2006, 83 (02) : 265 - 267
  • [6] Enhanced photocatalytic hydrogen production from aqueous sulfide/sulfite solution by ZnO0.6S0.4 with simultaneous dye degradation under visible-light irradiation
    Chu, Ka Him
    Ye, Liqun
    Wang, Wei
    Wu, Dan
    Chan, Donald Ka Long
    Zeng, Cuiping
    Yip, Ho Yin
    Yu, Jimmy C.
    Wong, Po Keung
    [J]. CHEMOSPHERE, 2017, 183 : 219 - 228
  • [7] European Commission, 2021, 2030 CLIMATE ENERGY, P180
  • [8] Solar photocatalytic destruction of p-nitrophenol:: A pedagogical use of lab wastes
    Herrera-Melián, JA
    Doña-Rodríguez, JM
    Rendón, ET
    Vila, AS
    Quetglas, MB
    Azcárate, AA
    Pariente, LP
    [J]. JOURNAL OF CHEMICAL EDUCATION, 2001, 78 (06) : 775 - 777
  • [9] Laboratory experiments on the electrochemical remediation of the environment
    Ibanez, JG
    Mayen-Mondragon, R
    Moran-Moran, MT
    Alatorre-Ordaz, A
    Mattson, B
    Eskestrand, S
    [J]. JOURNAL OF CHEMICAL EDUCATION, 2005, 82 (10) : 1546 - 1548
  • [10] The Basis for Photocatalytic Writing
    Ibanez, Jorge G.
    Tausch, Michael W.
    Bohrmann-Linde, Claudia
    Fernandez-Gallardo, Isabel
    Robles-Leyzaola, Ainoha
    Krees, Simone
    Meuter, Nico
    Tennior, Mathias
    [J]. JOURNAL OF CHEMICAL EDUCATION, 2011, 88 (08) : 1116 - 1118
123