Synthesis and photoactivity enhancement of Ba doped Bi2WO6 photocatalyst

被引:31
作者
Li, Wen Ting [1 ]
Huang, Wan Zhen [2 ]
Zhou, Huan [2 ]
Yin, Mao Yong [3 ]
Zheng, Yi Fan [2 ]
Song, Xu Chun [1 ]
机构
[1] Fujian Normal Univ, Dept Chem, Fuzhou 350007, Peoples R China
[2] Zhejiang Univ Technol, Res Ctr Anal & Measurement, Hangzhou 310014, Zhejiang, Peoples R China
[3] Hangzhou Dianzi Univ, Inst Environm Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R China
关键词
Inorganic compounds; Electron microscopy; X-ray diffraction; Catalytic properties; DEGRADATION; TIO2; NANOSHEETS;
D O I
10.1016/j.materresbull.2015.01.023
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, Bi2WO6 doped with different barium contents were successfully prepared by a simple hydrothermal route at 180 degrees C for 12 h. The as-synthesized samples were characterized in detailed by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis diffusere flectance spectroscopy (UV-vis DRS) and Brunauer-Emmet-Teller (BET) theory. Their photocatalytic activities were evaluated by photodegradation of Rhodamine B (RhB) under simulated solar light. As a result, the photocatalytic properties were enhanced after Ba doping and the Ba-doped Bi2WO6 with R-Ba = 0.15 showed the highest photocatalytic activities of 96.3% RhB was decomposed in 50 min. Close investigation revealed that the proper Ba doped into Bi2WO6 could not only increases its BET surface area, decrease its crystalline size, but also act as electron traps and facilitate the separation of photogenerated electron-hole pairs. The mechanism of enhanced photocatalytic activities of Ba-doped Bi2WO6 were further investigated. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:432 / 437
页数:6
相关论文
共 24 条
[1]   Preparation, characterization, and photoactivity of polycrystalline nanostructured TiO2 catalysts [J].
Addamo, M ;
Augugliaro, V ;
Di Paola, A ;
García-López, E ;
Loddo, V ;
Marci, G ;
Molinari, R ;
Palmisano, L ;
Schiavello, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (10) :3303-3310
[2]  
[Anonymous], 2012, INT J PHOTOENERGY, DOI DOI 10.1109/APPEEC.2012.6307734
[3]   Photodegradation of bisphenol A by highly stable palladium-doped mesoporous graphite carbon nitride (Pd/mpg-C3N4) under simulated solar light irradiation [J].
Chang, Chun ;
Fu, Yu ;
Hu, Meng ;
Wang, Chunying ;
Shan, Guoqiang ;
Zhu, Lingyan .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 142 :553-560
[4]   The effect of carbon content on the structure and photocatalytic activity of nano-Bi2WO6 powder [J].
Cui, Yumin ;
Li, Huiquan ;
Hong, Wenshan ;
Fan, Suhua ;
Zhu, Liangjun .
POWDER TECHNOLOGY, 2013, 247 :151-160
[5]   Visible-light-induced degradation of rhodamine B by nanosized Bi2WO6 [J].
Fu, HB ;
Pan, CS ;
Yao, WQ ;
Zhu, YF .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (47) :22432-22439
[6]   Enhanced photocatalytic performance of boron doped Bi2WO6 nanosheets under simulated solar light irradiation [J].
Fu, Yu ;
Chang, Chun ;
Chen, Peng ;
Chu, Xiaolong ;
Zhu, Lingyan .
JOURNAL OF HAZARDOUS MATERIALS, 2013, 254 :185-192
[7]   Density functional characterization of C-doped anatase TiO2 with different oxidation state [J].
Gao, Hongtao ;
Ding, Cuihong ;
Dai, Dongmei .
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2010, 944 (1-3) :156-162
[8]   Fe-ions modified mesoporous Bi2WO6 nanosheets with high visible light photocatalytic activity [J].
Guo, Sen ;
Li, Xiaofang ;
Wang, Haiqiang ;
Dong, Fan ;
Wu, Zhongbiao .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 369 :373-380
[9]   Micro/nano-structured CaWO4/Bi2WO6 composite: synthesis, characterization and photocatalytic properties for degradation of organic contaminants [J].
Guo, Yadan ;
Zhang, Gaoke ;
Gan, Huihui ;
Zhang, Yalei .
DALTON TRANSACTIONS, 2012, 41 (41) :12697-12703
[10]   Synthesis and Photocatalytic Properties of N/Bi2WO6 Flower-like Crystallites Self-Assembled from Nanoflakes [J].
Huang, Jing ;
Tan, Guo-Qiang ;
Yang, Wei ;
Zhang, Li-Li ;
Ren, Hui-Jun ;
Xia, Ao .
JOURNAL OF CLUSTER SCIENCE, 2013, 24 (04) :1139-1149