High-Efficiency Graphene-Oxide/Silicon Solar Cells with an Organic-Passivated Interface

被引：13
作者：
Gao, Qing [1 ]
Yan, Jun [1 ]
Wan, Lu [1 ]
Zhang, Cuili [1 ]
Wen, Zhixi [1 ]
Zhou, Xin
Li, Han [2 ]
Li, Feng [3 ]
Chen, Jingwei [1 ]
Guo, Jianxin [1 ]
Song, Dengyuan [1 ]
Flavel, Benjamin S. [2 ]
Chen, Jianhui [1 ]
机构：
[1] Hebei Univ, Hebei Key Lab Opt Elect Informat & Mat, Coll Phys Sci & Technol, Baoding 071002, Peoples R China
[2] Karlsruhe Inst Technol, Inst Nanotechnol, D-76344 Eggenstein Leopoldshafen, Germany
[3] Yingli Green Energy Holding Co Ltd, State Key Lab Photovolta Mat & Technol, Baoding 071051, Peoples R China
来源：
ADVANCED MATERIALS INTERFACES | 2022年 / 9卷 / 24期
基金：
中国国家自然科学基金;
关键词：
graphene; organic passivation; photovoltaic; reduced graphene oxide; silicon solar cells; METAL-OXIDES; HETEROSTRUCTURE; ELECTRODES; CONTACTS;
D O I：
10.1002/admi.202201221
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A breakthrough in graphene-oxide/silicon heterojunction solar cells is presented in which edge-oxidized graphene and an in-plane charge transfer dopant (Nafion) are combined to form a high-quality passivating contact scheme. A graphene oxide (GO):Nafion ink is developed and an advanced back-junction GO:Nafion/n-Si solar cell with a high-power conversion efficiency (18.8%) and large area (5.5 cm(2)) is reported. This scalable solution-based processing technique has the potential to enable low-cost carbon/silicon heterojunction photovoltaic devices.
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页数：7
相关论文
共 43 条
[1]   Passivating contacts for crystalline silicon solar cells [J].
Allen, Thomas G. ;
Bullock, James ;
Yang, Xinbo ;
Javey, Ali ;
De Wolf, Stefaan .
NATURE ENERGY, 2019, 4 (11) :914-928
[2]   Junction characteristics of chemically-derived graphene/p-Si heterojunction solar cell [J].
Behura, Sanjay K. ;
Nayak, Sasmita ;
Mukhopadhyay, Indrajit ;
Jani, Omkar .
CARBON, 2014, 67 :766-774
[3]   Temperature and light dependent electrical properties of Graphene/n-Si-CH3-terminated solar cells [J].
Brus, V. V. ;
Gluba, M. A. ;
Zhang, X. ;
Hinrichs, K. ;
Rappich, J. ;
Nickel, N. H. .
SOLAR ENERGY, 2014, 107 :74-81
[4]   Stability of graphene-silicon heterostructure solar cells [J].
Brus, V. V. ;
Gluba, M. A. ;
Zhang, X. ;
Hinrichs, K. ;
Rappich, J. ;
Nickel, N. H. .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2014, 211 (04) :843-847
[5]   Front and Back-Junction Carbon Nanotube-Silicon Solar Cells with an Industrial Architecture [J].
Chen, Jianhui ;
Tune, Daniel D. ;
Ge, Kunpeng ;
Li, Han ;
Flavel, Benjamin S. .
ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (17)
[6]   Vacuum-Free, Room-Temperature Organic Passivation of Silicon: Toward Very Low Recombination of Micro-/Nanotextured Surface Structures [J].
Chen, Jianhui ;
Ge, Kunpeng ;
Zhang, Cuili ;
Guo, Jianxin ;
Yang, Linlin ;
Song, Dengyuan ;
Li, Feng ;
Xu, Zhuo ;
Xu, Ying ;
Mai, Yaohua .
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (51) :44890-44896
[7]   Achievement of two logical states through a polymer/silicon interface for organic-inorganic hybrid memory [J].
Chen, Jianhui ;
Chen, Bingbing ;
Shen, Yanjiao ;
Guo, Jianxin ;
Liu, Baoting ;
Dai, Xiuhong ;
Xu, Ying ;
Mai, Yaohua .
APPLIED PHYSICS LETTERS, 2017, 111 (19)
[8]   Silicon surface passivation by polystyrenesulfonate thin films [J].
Chen, Jianhui ;
Shen, Yanjiao ;
Guo, Jianxin ;
Chen, Bingbing ;
Fan, Jiandong ;
Li, Feng ;
Liu, Haixu ;
Xu, Ying ;
Mai, Yaohua .
APPLIED PHYSICS LETTERS, 2017, 110 (08)
[9]   The Effect of Thermal Reduction on the Photoluminescence and Electronic Structures of Graphene Oxides [J].
Chuang, C-H ;
Wang, Y-F. ;
Shao, Y-C. ;
Yeh, Y-C. ;
Wang, D-Y. ;
Chen, C-W. ;
Chiou, J. W. ;
Ray, Sekhar C. ;
Pong, W. F. ;
Zhang, L. ;
Zhu, J. F. ;
Guo, J. H. .
SCIENTIFIC REPORTS, 2014, 4
[10]   Charge transport in organic semiconductors [J].
Coropceanu, Veaceslav ;
Cornil, Jerome ;
da Silva Filho, Demetrio A. ;
Olivier, Yoann ;
Silbey, Robert ;
Bredas, Jean-Luc .
CHEMICAL REVIEWS, 2007, 107 (04) :926-952
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