Biosorption of Pb(II) and Cd(II) ions from aqueous solution using polyaniline/chitin composite

被引:22
作者
Karthik, Rathinam [1 ]
Meenakshi, Sankaran [1 ]
机构
[1] Gandhigram Rural Inst Deemed Univ, Dept Chem, Dindigul 624302, Tamil Nadu, India
关键词
kinetics; Adsorption; chitin; polyaniline; HEXAVALENT CHROMIUM; MODIFIED FORMS; REMOVAL; CHITOSAN; ADSORPTION; CHITIN; WATER;
D O I
10.1080/01496395.2015.1130060
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, chitin (Ch) was made composite with polyaniline (PANI) and used for the removal of Pb(II) and Cd(II) ions from aqueous solution. Characterization techniques such as Fourier transform infrared spectroscopy, scanning electron microscope, energy-dispersive X-ray analyser and X-ray diffraction were employed to characterize the prepared PANI/Ch composite. Influence of various equilibrium parameters on the adsorption of Pb(II) and Cd(II) ions onto PANI/Ch composite was investigated. The adsorption process followed the Freundlich isotherm model, and the calculated maximum monolayer sorption capacity of PANI/Ch composite for Pb(II) and Cd(II) ions is 7.03 and 6.05 mg g(-1) at 303 K. The kinetic data were well described by the pseudo-second-order model.
引用
收藏
页码:733 / 742
页数:10
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