Comment on "Development of Correlations for Describing Solute Transfer into Acyclic Alcohol Solvents Based on the Abraham Model and Fragment-Specific Equation Coefficients"

被引：4

作者：

Endo, Satoshi ^{[1
]}

Goss, Kai-Uwe ^{[1
]}

机构：

[1] UFZ Helmholtz Ctr Environm Res, Dept Analyt Environm Chem, D-04318 Leipzig, Germany

来源：

FLUID PHASE EQUILIBRIA | 2010年 / 291卷 / 02期

关键词：

D O I：

10.1016/j.fluid.2010.01.004

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Partitioning coefficients into differing acyclic aliphatic alcohols can be described by the linear solvation energy relationship (LSER) equations with 6 fitting parameters to the accuracy of 0.19-0.20 log units. If 6 more fitting parameters are added to account for the slight dependency of the partitioning coefficients on the number of carbon atoms of alcohols, the accuracy improves to 0.15-0.16, comparable to the performance by the 30-parameter model proposed by Sprunger et al. [1]. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：212 / 213

页数：2