Synthesis, Spectral, and Antimicrobial Studies of Nickel(II) Complexes With Nitrogen-Containing Ligands

被引：7

作者：

Omoregie, H. Oluwatola ^{[1
]}

Ojattah, P. ^{[1
]}

Adeleke, O. E. ^{[2
]}

Woods, J. A. O. ^{[1
]}

Capitelli, F. ^{[3
]}

机构：

[1] Univ Ibadan, Dept Chem, Fac Sci, Ibadan, Nigeria

[2] Univ Ibadan, Dept Pharmaceut Microbiol, Ibadan, Nigeria

[3] CNR, Inst Crystallog, I-00016 Monterotondo, Italy

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2015年 / 45卷 / 04期

关键词：

X-ray; spectral measurements; antimicrobial studies; elemental analysis; conductance; INFRA-RED SPECTRA; 1,10-PHENANTHROLINE; COPPER(II); ADDUCTS;

D O I：

10.1080/15533174.2013.841202

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some nickel(II) complexes of 1,10-phenanthroline and 2,2 '-bipyridine, associated with counterions such as Cl-, NO3-, OAc-, and SO42- have been synthesized and characterized by elemental analysis, conductance, spectral measurements, and antimicrobial studies. The conductance measurement indicates that [Ni(bipy)(2)H2O(NO3)](NO3), [Ni(phen)(2)(H2O)Cl]Cl center dot 3H(2)O center dot CH3OH and [Ni(phen)(3)](NO3)(2).4H(2)O are 1:1 and 1:2 electrolytes, respectively. The infrared and electronic spectral studies are consistent with the adoption of probable six-coordinate octahedral geometry for the complexes. The microbiostatic activity revealed that all the complexes showed pronounced activity against the tested fungi but little or no antibacterial activity. A six-coordinate octahedral geometry was established for [Ni(phen)(2)(H2O)Cl]Cl center dot 3H(2)O center dot CH3OH using X-ray crystallography.

引用

页码：469 / 475

页数：7

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