Electrical transport properties of polyaniline grafted radiation crosslinked chitosan

被引:2
作者
Ramaprasad, A. T. [1 ,2 ,3 ]
Sanjeev, Ganesh [4 ]
Rao, Vijayalakshmi [3 ]
机构
[1] Alvas Inst Engn & Technol, Dept Engn Phys, Shobhavana Campus, Mangalore 574225, Karnataka, India
[2] Visvesrayya Technol Univ, Belagavi, India
[3] Mangalore Univ, Dept Mat Sci, Mangalore 574199, Karnataka, India
[4] Mangalore Univ, Micrtron Ctr, Mangalore 574199, Karnataka, India
关键词
Electrical characterization; Electrical conductivity; Dielectric properties polymers; Polyaniline; Chitosan;
D O I
10.1016/j.matpr.2020.01.538
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Present work reports about electrical properties of polyaniline (PANI) grafted with electron beam crosslinked chitosan. Measurement of temperature dependent dc & ac conductivity shows a significant improvement in the ac and dc conductivity after doping with 1 M HCl for different time intervals. The dc conductivity results were analyzed using Mott's variable range hopping mechanism. The ac conductivity of grafted polymer obeys power law and behavior of frequency exponent's' has been interpreted by the correlated barrier hopping (CBH) model. The variation of dielectric constant with temperature and frequency is consistent with the Debye type dispersion. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码:318 / 324
页数:7
相关论文
共 34 条
[31]   Electrochemical detection of a breast cancer susceptible gene using cDNA immobilized chitosan-co-polyaniline electrode [J].
Tiwari, Ashutosh ;
Gong, Shaoqin .
TALANTA, 2009, 77 (03) :1217-1222
[32]   EFFECT OF DOPANT ON THE PHYSICOCHEMICAL AND ELECTRICAL-PROPERTIES OF ORGANIC CONDUCTING POLYMERS [J].
TOURILLON, G ;
GARNIER, F .
JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (13) :2289-2292
[33]  
WANG GH, 1987, NUCL INSTRUM METH B, V27, P410, DOI 10.1016/0168-583X(87)90521-0
[34]   CHITALINE MATERIALS - SOLUBLE CHITOSAN-POLYANILINE COPOLYMERS AND THEIR CONDUCTIVE DOPED FORMS [J].
YANG, S ;
TIRMIZI, SA ;
BURNS, A ;
BARNEY, AA ;
RISEN, WM .
SYNTHETIC METALS, 1989, 32 (02) :191-200