Present work reports about electrical properties of polyaniline (PANI) grafted with electron beam crosslinked chitosan. Measurement of temperature dependent dc & ac conductivity shows a significant improvement in the ac and dc conductivity after doping with 1 M HCl for different time intervals. The dc conductivity results were analyzed using Mott's variable range hopping mechanism. The ac conductivity of grafted polymer obeys power law and behavior of frequency exponent's' has been interpreted by the correlated barrier hopping (CBH) model. The variation of dielectric constant with temperature and frequency is consistent with the Debye type dispersion. (C) 2019 Elsevier Ltd. All rights reserved.
机构:
Univ Wisconsin, Dept Mech Engn, Milwaukee, WI 53201 USAUniv Wisconsin, Dept Mech Engn, Milwaukee, WI 53201 USA
Tiwari, Ashutosh
;
Gong, Shaoqin
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机构:
Univ Wisconsin, Dept Mech Engn, Milwaukee, WI 53201 USA
Univ Wisconsin, Dept Mat, Milwaukee, WI USAUniv Wisconsin, Dept Mech Engn, Milwaukee, WI 53201 USA
机构:
Univ Wisconsin, Dept Mech Engn, Milwaukee, WI 53201 USAUniv Wisconsin, Dept Mech Engn, Milwaukee, WI 53201 USA
Tiwari, Ashutosh
;
Gong, Shaoqin
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Mech Engn, Milwaukee, WI 53201 USA
Univ Wisconsin, Dept Mat, Milwaukee, WI USAUniv Wisconsin, Dept Mech Engn, Milwaukee, WI 53201 USA