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Hydrothermal Synthesis of TiO2/WO3 Compositions And Their Photocatalytic Activity
被引:0
|作者:
Pyachin, Sergey A.
[1
]
Karpovich, Natalia F.
[1
]
Zaitsev, Alexey V.
[1
]
Makarevich, Konstantin S.
[1
]
Burkov, Alexander A.
[1
]
Ustinov, Alexander Yu.
[2
]
机构:
[1] Russian Acad Sci, Far Eastern Branch, Khabarovsk Sci Ctr, Inst Mat, 153 Tikhookeanskaya St, Khabarovsk 680042, Russia
[2] Russian Acad Sci, Far Eastern Branch, Inst Chem, 159 Pr 100 Letiya Vladivostoka, Vladivostok 690022, Russia
来源:
ASIA-PACIFIC CONFERENCE ON FUNDAMENTAL PROBLEMS OF OPTO- AND MICROELECTRONICS
|
2017年
/
10176卷
关键词:
photocatalysis;
titanium dioxide;
tungsten oxide;
doping;
hydrothermal synthesis;
diffuse reflection;
band gap;
photocatalytic activity;
D O I:
10.1117/12.2268789
中图分类号:
TM [电工技术];
TN [电子技术、通信技术];
学科分类号:
0808 ;
0809 ;
摘要:
Photocatalytic activity, optical properties, thermal stability, phase patterns and morphology of nano-size. TiO2/WO3 compositions obtained from organic precursors through hydrothermal synthesis have been studied. It has been shown that doping of anatase nanoparticles with tungsten W+6 results in particle diameter reduction from 35 to 10 nm; decrease in width of the band gap from 3.15 eV to 2.91 eV and increase in temperature of phase transition of anatase to rutile up to 980 degrees C . Catalytic activity of TiO2/WO3 (4 mol.%) composition under photochemical methylene blue (MB) oxidation by simulated solar light exceeds that of undoped anatase (obtained in the same way) 6-fold.
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