Two Chain Like B-Type-Anderson-Based Hybrids Synthesized in Choline Chloride/Urea Eutectic Mixture

被引：21
|
作者：
Wang, Shi-Ming [1 ]
Chen, Wei-Lin [1 ]
Wang, En-Bo [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci Minist Educ, Changchun 130024, Jilin, Peoples R China
来源：
JOURNAL OF CLUSTER SCIENCE | 2010年 / 21卷 / 02期
关键词：
Eutectic mixture; Ionic liquids; B-Anderson type; Polyoxometalate; INORGANIC-ORGANIC HYBRIDS; IONOTHERMAL SYNTHESIS; IONIC LIQUIDS; POLYOXOMETALATE CLUSTERS; COORDINATION POLYMER; COMPLEXES; SOLVENT; ALUMINOPHOSPHATE; POLYOXOANIONS; FRAMEWORKS;
D O I：
10.1007/s10876-010-0301-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new chain like B-Anderson type polyoxomolybdates based hybrids {Na[(CH(3))(3)N(CH(2))(2)OH](2)}[Al(OH)(6)Mo(6)O(18)]center dot 2(NH(2)CONH(2))center dot 6H(2)O (1) and {Na[(CH(3))(3)N(CH(2))(2)OH](2)}[Cr(OH)(6)Mo(6)O(18)]center dot 2(NH(2)CONH(2))center dot 6H(2)O (2) were synthesized in choline chloride/urea eutectic mixture and characterized by element analysis, IR, UV-vis, TG, single-crystal X-ray analysis, and power X-ray diffraction. Through the linkage [Na(H(2)O)(2)(NH(2)CONH(2))(2)](+), the [X(OH)(6)Mo(6)O(18)](3-) (X = Al, Cr) units are arranged into a chain. Considering hydrogen bonding interactions between the chains, compound 1 and 2 are all well-arranged into 3-D supermolecular assembly. The structure is first obtained in the choline chloride/urea eutectic mixture.
引用
收藏
页码：133 / 145
页数：13
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