Environment-friendly organic synthesis. The photochemical approach

被引:60
作者
Albini, A [1 ]
Fagnoni, M [1 ]
Mella, M [1 ]
机构
[1] Univ Pavia, Dept Organ Chem, I-27100 Pavia, Italy
关键词
D O I
10.1351/pac200072071321
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photochemical reactions are expected to have an increasing role in organic synthesis with the drive towards environment-friendly reactions. Some examples illustrating the scope and versatility of radical alkylation of electrophilic alkenes via photoinduced electron transfer are presented. A few applications in special fields are mentioned.
引用
收藏
页码:1321 / 1326
页数:6
相关论文
共 55 条
[21]   ALKYL RADICALS FROM T-BUTYL ESTERS THROUGH PHOTOINDUCED ELECTRON-TRANSFER [J].
FASANI, E ;
PEVERALI, D ;
ALBINI, A .
TETRAHEDRON LETTERS, 1994, 35 (49) :9275-9278
[22]   Photo-induced depolymerization of reversible supramolecular polymers [J].
Folmer, BJB ;
Cavini, E ;
Sijbesma, RP ;
Meijer, EW .
CHEMICAL COMMUNICATIONS, 1998, (17) :1847-1848
[23]  
FOZ MA, 1988, PHOTOINDUCED ELECT T
[24]   A kinetic evaluation of carbon-hydrogen, carbon-carbon, and carbon-silicon bond activation in benzylic radical cations [J].
Freccero, M ;
Pratt, A ;
Albini, A ;
Long, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (02) :284-297
[25]   Photoinduced electron transfer bond fragmentations [J].
Gaillard, ER ;
Whitten, DG .
ACCOUNTS OF CHEMICAL RESEARCH, 1996, 29 (06) :292-297
[26]   The ionic auxiliary concept in solid state organic photochemistry [J].
Gamlin, JN ;
Jones, R ;
Leibovitch, M ;
Patrick, B ;
Scheffer, JR ;
Trotter, J .
ACCOUNTS OF CHEMICAL RESEARCH, 1996, 29 (04) :203-209
[27]   Photoinduced decarboxylation reactions -: Radical chemistry in water [J].
Griesbeck, AG ;
Kramer, W ;
Oelgemöller, M .
GREEN CHEMISTRY, 1999, 1 (04) :205-207
[28]  
Horspool W.M., 1995, CRC HDB ORGANIC PHOT
[29]  
ITO Y, 1999, ORGANIC MOL PHOTOCHE, P1
[30]   PHOTOSENSITIZATION BY REVERSIBLE ELECTRON-TRANSFER - THEORIES, EXPERIMENTAL-EVIDENCE, AND EXAMPLES [J].
KAVARNOS, GJ ;
TURRO, NJ .
CHEMICAL REVIEWS, 1986, 86 (02) :401-449