Environment-friendly organic synthesis. The photochemical approach

被引:60
作者
Albini, A [1 ]
Fagnoni, M [1 ]
Mella, M [1 ]
机构
[1] Univ Pavia, Dept Organ Chem, I-27100 Pavia, Italy
关键词
D O I
10.1351/pac200072071321
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photochemical reactions are expected to have an increasing role in organic synthesis with the drive towards environment-friendly reactions. Some examples illustrating the scope and versatility of radical alkylation of electrophilic alkenes via photoinduced electron transfer are presented. A few applications in special fields are mentioned.
引用
收藏
页码:1321 / 1326
页数:6
相关论文
共 55 条
[1]   RADICAL CATIONS - GENERATION BY PHOTOCHEMICAL ELECTRON-TRANSFER AND FRAGMENTATION [J].
ALBINI, A ;
FASANI, E ;
DALESSANDRO, N .
COORDINATION CHEMISTRY REVIEWS, 1993, 125 (1-2) :269-281
[2]  
AMSTRONG RW, 1995, Patent No. 02566
[3]  
[Anonymous], ORG PHOTOCHEM
[4]  
[Anonymous], TOP CURR CHEM
[5]  
[Anonymous], TOP CURR CHEM
[6]  
[Anonymous], 1989, PHOTOCHEMICAL SYNTHE
[7]  
[Anonymous], 1992, ORGANIC PHOTOCHEMIST
[8]   RADICAL IONS IN PHOTOCHEMISTRY .3. PHOTOSENSITIZED (ELECTRON-TRANSFER) CLEAVAGE OF BETA-PHENETHYL ETHERS [J].
ARNOLD, DR ;
MAROULIS, AJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (19) :5931-5936
[9]   OXIDATION POTENTIALS OF CIS-1,2-DIPHENYLCYCLOPROPANE AND TRANS-1,2-DIPHENYLCYCLOPROPANE AND CIS-2,3-DIPHENYLOXIRANE AND TRANS-2,3-DIPHENYLOXIRANE [J].
ARNOLD, DR ;
WONG, PC .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1979, 57 (16) :2098-2102
[10]   Enantiodifferentiating anti-Markovnikov photoaddition of alcohols to 1,1-diphenylalkenes sensitized by chiral naphthalenecarboxylates [J].
Asaoka, S ;
Kitazawa, T ;
Wada, T ;
Inoue, Y .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (37) :8486-8498