Synthesis and properties of 1,5-dithio-3-oxa-pentanediyl bridged polymeric phthalocyanines

被引：13

作者：

Agar, E ^{[1
]}

Sasmaz, S ^{[1
]}

Keskin, I ^{[1
]}

Karabulut, B ^{[1
]}

机构：

[1] ONDOKUZ MAYIS UNIV,DEPT PHYS,TR-55139 KURUPELIT,SAMSUN,TURKEY

来源：

DYES AND PIGMENTS | 1997年 / 35卷 / 03期

关键词：

phthalocyanine polymers; dithio-oxa-ether;

D O I：

10.1016/S0143-7208(96)00112-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Oxa-thio bridged metal-free and metal phthalocyanine polymers were prepared. Metal-free phthalocyanine polymer (H2Pc) and metal phthalocyanine polymers (Ni, Cu, Co, Zn or Fe) carrying dithio-oxa bridged were synthesized from 3, 3' - 4, 4'-tetracyanodiphenyl-1, 5-dithiopentanyl-oxa-ether and hydroquinone or the corresponding anhydrous metal salts [NiCl2, CuCl, CoCl2, Zn(CH3CO2)(2) or Fe(CO)(5)]. The model phthalocyanine compounds were characterized by IR, UV/VIS and DTA. The electrical conductivities of the phthalocyanines measured as gold sandwiches are about 10(-10)S m(-1) in vacuo and in air. (C) 1997 Elsevier Science Ltd.

引用

页码：269 / 278

页数：10

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