Passivation of aluminum with alkyl phosphonic acids for biochip applications

被引:36
作者
Attavar, Sachin [1 ]
Diwekar, Mohit [1 ]
Linford, Matthew R. [2 ]
Davis, Mark A. [3 ]
Blair, Steve [1 ]
机构
[1] Univ Utah, Dept Elect Engn, Salt Lake City, UT 84112 USA
[2] Brigham Young Univ, Dept Chem & Biochem, Provo, UT 84602 USA
[3] MOXTEK Inc, Orem, UT 84057 USA
关键词
Biosenor; DNA metallic microarray; Phosphonic acid self-assembled monolayer; SELF-ASSEMBLED MONOLAYERS; ALKANEPHOSPHATE MONOLAYERS; SURFACE MODIFICATION; ADSORPTION; MOLECULES; TITANIUM;
D O I
10.1016/j.apsusc.2010.05.041
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Self-assembly of decylphosphonic acid (DPA) and octadecylphosphonic acid (ODPA) was studied on aluminum films using XPS, ToF-SIMS and surface wettability. Modified aluminum films were tested for passivation against silanization and subsequent oligonucleotide attachment. Passivation ratios of at least 450: 1 compared to unprotected aluminum were obtained, as quantified by attachment of radio-labeled oligos. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:7146 / 7150
页数:5
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